The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
The addition of small quantities of a solution of certain substances to
a stiff clay paste usually reduces its stiffness, and in some cases
turns it into a liquid. The alkalies are particularly powerful in this
respect and their action may be strikingly illustrated by mixing a few
drops of caustic soda with a stiff clay paste. In a few moments the
mixture will be sufficiently liquid to pour readily, but it may be
rendered quite stiff again by adding sufficient acid to neutralize the
alkali previously used. Weber (12) has utilized this characteristic to
great advantage in the production of sanitary ware and crucibles for
glass-making by a process of casting which he has patented.
The effect of adding water to a dry clay is curious. At first the
particles in contact with the water become sticky and plastic, and if
the proportion of water added is suitable and the mixing is sufficiently
thorough a plastic mass will be produced, the characteristics of which
will depend on the nature of the clay used. This process of mixing clay
with a limited amount of water is known as 'tempering.' The proportion
of water required to make a paste of suitable consistency for modelling
appears to be constant for each clay. If, however, a larger proportion
of water is added the particles of clay will be separated so widely from
each other that they lose their cohesion, and instead of a plastic mass,
the material will form a liquid of cream-like consistency. If a piece of
stiff clay paste is suspended in a large volume of water without
stirring, disintegration will still occur (though a much longer time
will be required) and the clay will be deposited as a sediment at the
bottom of the vessel. The leaner the clay or the larger the proportion
of non-plastic material it contains, the more rapidly will this
disintegration take place. A highly plastic clay will become almost
impervious and will retain its shape indefinitely.
If a mixture of clay and water in the form of a cream or slurry be
allowed to rest, the larger and less plastic particles will settle, but
many of the particles of true clay will remain suspended for several
hours and some of them for several days. Some particles of clay are so
small that it is doubtful if they would ever settle completely unless
some coagulant were added, and as they readily pass through all ordinary
filtering media it is extremely difficult to collect them in a pure
state. These turbid suspensions of clay may be rapidly cleared by the
addition of sodium chloride which increases the surface tension of the
solution. The fine particles behave in the same way as colloidal
substances, _i.e._ as if they possessed an electrostatic charge. Hence
the addition of a salt (electrolyte), whose ions annul the opposite
charges of the electric double layer assumed by Helmholtz to be present,
enables the particles to coagulate in accordance with the ordinary laws
of surface tension (14).
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