The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
Porosity may thus be regarded as the opposite of vitrification; porous
goods being relatively light and soft whilst vitrified ones are dense
and hard. For some purposes, porosity is an important characteristic:
for example, building bricks which are moderately porous are preferable
to those which are vitrified. The manufacture of porous blocks for the
construction of light, sound-proof partitions, etc. has increased
rapidly of late. They are made by adding sawdust or other combustible
material to the clay. The added substances burn out on firing the goods
in a kiln.
Clays which are porous can be dried more readily and with less risk of
cracking than those which are more dense. For this reason, some
clayworkers mix non-plastic material such as sand or burned clay with
their raw material.
The _impermeability_ of plastic clay to water is a characteristic which
is important for many purposes.
The _absorptive power_ of clays is closely related to their porosity so
far as pure water is concerned, but if the water contains certain salts
in solution a selective absorption occurs, the bases being retained by
the clay in such a manner that they cannot be removed by washing. The
selective action is known as _adsorption_ and is most noticeable in
highly plastic clays. Bourry (10) has shown that the slightly plastic
china clays only exercise a small power of adsorbing calcium carbonate
from solution, but highly plastic clays may adsorb 20 per cent. of it.
The alkaline chlorides and sulphates do not appear to be adsorbed in
this manner, but the carbonates are readily removed from solution. All
calcium and magnesium compounds appear to be adsorbed, though in
variable quantities, the reaction being complicated when several soluble
salts are present. Ries (6) has found that gallo-tannic acid is adsorbed
readily and increases the plasticity of clay.
Ashley (11) has endeavoured to measure the plasticity of clays by
determining their adsorption capacity for various aniline dyes, but his
untimely decease prevented the investigation being completed. There is
reason to suppose that the relation between adsorption and plasticity is
extremely close in many clays and that the former may, to an important
extent, be used as a measure of the latter. In some clays, however, this
relationship does not exist.
Sand and burned clay only show faint adsorption phenomena; felspar shows
them to a slight and almost negligible extent and most of the other
non-plastic ingredients of clays are non-adsorptive.
Selective adsorption being an important characteristic of colloidal
substances, the possession of this power by plastic clays supports the
claim that plasticity is due, at least in part, to the presence of
colloids.
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