The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
The recent progress made in the application of the laws of physical
chemistry to geological problems is continually throwing fresh light on
this interesting subject. Thus, studies of the dissociation pressures
and transition points between the anhydrous and the hydrous states of
various substances and the effect of water as a powerful agent of
decomposition (hydrolysis) have shown that hydration is a
characteristic result of decompositions occurring in the upper portions
of the earth's crust and not in the lower ones, and that it is usually
checked, or even reversed, when the substance is under great pressure.
At great depths kaolins and other complex hydrous silicates give place
to anhydrous ones such as muscovite, andalusite and staurolite. There
is, therefore, good reason to believe that the kaolinization of Cornish
felspar has occurred at only moderate depths from the surface and that
it has been chiefly produced by the action of water containing acid
gases in solution. The acid in the water may have been absorbed from the
atmosphere, or it may be due to vapours rising from below through the
felspathic material.
In Great Britain, china clay occurs in the form of powdery particles
apparently amorphous, but containing some crystals, scattered through a
mass of harder rock, the whole being known as china clay rock or
'carclazite.' The softer portions of this china clay rock are known as
'growan' and the china clay in it represents only a small proportion of
the whole material.
The finer particles of clay and other materials are removed by treatment
with water, whereby one-third to one-eighth of the material is
separated. This small proportion is then subjected to further washing
and sedimentation in order to obtain the china clay in a state of
commercial purity. It will thus be understood that the Cornish china
clays are not 'deposits' in the usual acceptation of that term, the soft
growan from which they are obtained being almost invariably the result
of decomposition _in situ_ of some species of felspar in disintegrated
granite.
The commercial kaolins of France, Germany, America and China very
closely resemble the Cornish china clays in composition, but when used
in the manufacture of porcelain they create differences in the finished
material which are clearly noticeable, though microscopical examination
and chemical analysis, at present, fail to distinguish between them in
the raw state on account of their great resistance to ordinary chemical
and physical forces.
In addition to the breaking up of felspathic rocks with the formation of
china clay or kaolin (kaolinization), other decompositions which occur
may result in the formation of clays, and an examination of a
considerable number of clays by J. M. van Bemmelen (26) has led him to
suppose that several different clay-forming forces have been at work in
the production of clays. He classifies these under four heads:
Public-domain text, read in full here on John Shaqi.
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