The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
(1) _Kaolinization_, or the decomposition of felspathic and similar
rocks by the action of telluric water containing active gases in
solution.
(2) _Ordinary weathering_ in which the action is largely mechanical, but
is accompanied by some hydrolysis owing to the impurities contained in
the water which is an essential factor.
(3) _Lateritic action_--or simple decomposition by heat--which occurs
chiefly under tropical conditions, but may also occur in temperate
climates, and has for its main product a mixture of free silica and
alumina, the latter being in the form of (amorphous) 'laterite.' It may
not improbably be a result of the decomposition of the clay molecule
similar to that which occurs when china clay is heated, as there is no
temperature below which it can be said that china clay does not
decompose into free silica and alumina (29).
(4) _Secondary reactions_ in which the products of one of the reactions
previously described may undergo further changes, as the conversion of
amorphous clayite into crystalline kaolinite, or amorphous laterite into
crystalline hydrargillite.
Weathering.
The action of the forces conveniently classed under the term
_weathering_ are of two main kinds:
(_a_) The _mechanical grinding_ of sandstone, quartzite, limestone, and
other rocks, causes an addition of adventitious material to clay, the
proportions being sometimes so large as to render it necessary to term
the material an argillaceous sand, rather than a sandy clay. Some of
these grains of mineral matter are so minute and so resistant to the
ordinary chemical reagents as to make it extremely difficult to
distinguish them from clay.
(_b_) The _chemical decomposition_ due to the action of very dilute
solutions. By this means simple silicates are decomposed with the
formation of colloidal silica which may either remain in solution or may
be deposited in a coagulated form. At the same time, some
alumino-silicates will be similarly decomposed into colloidal
alumino-silicic acids or clays.
The ultimate results of the action of ordinary weathering on silicate
rocks are, therefore, sands and clays, the latter being in some ways
quite distinct in their origin and physical properties from the china
clays. According to J. M. van Bemmelen (26) such clays also contain an
alumino-silicate soluble in boiling hydrochloric acid followed by
caustic soda, whereas pure china clays are unaffected by this treatment.
The variety of silicates and other minerals which--in a partially
decomposed condition--go to form 'clays' is so great that the complete
separation of the smallest particles of them from those of the true clay
present has never been accomplished and our knowledge of the
mineralogical constitution of many of the best known clays is far from
complete.
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