The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
Potash and soda compounds are commonly present as constituents of the
felspar, mica, or other silicates present, and need no further
description, though small proportions of _soluble salts_--chiefly
sodium, potassium, calcium and magnesium sulphates--occur in most clays
and may cause a white scum on bricks and terra-cotta made from them.
_Lime and magnesia compounds_ may occur as silicates (varieties of
felspar, mica, etc.), but their most important occurrence is as chalk or
limestone. _Chalk_ is a constant constituent of malms[2] and of many
marls, but the latter may contain limestone particles. _Limestone_
occurs in many marls and to a smaller extent in other clays. In the
boulder clays it frequently forms a large portion of the stony material.
If the grains are very small (as in chalk), the lime compounds act as a
flux, reducing the heat-resisting power of the clay and increasing the
amount of vitrification; they produce in extreme cases a slag-like mass
when the clay is intensely heated. If, on the contrary, the grains are
larger (as frequently occurs with limestone), they are converted into
lime or magnesia when the clay is 'burned' in a kiln, and the lime, on
exposure to weather, absorbs moisture (_i.e. slakes_), swells, and may
disintegrate the articles made from the clay. Limestone (except when in
a very finely divided state) is almost invariably objectionable in
clays, but chalk is frequently a valuable constituent.
[Footnote 2: A _malm_ is a natural mixture of clay and chalk (p. 68).]
Chalk is added to clay in the manufacture of malm-bricks to produce a
more pleasing colour than would be obtained from the clay alone, to
reduce the shrinkage of the clay to convenient limits and, less
frequently, to form a more vitrifiable material. Chalk, on heating,
combines with iron oxide and clay, forming a white silicate, so that
some clays which would, alone, form a red brick, will, if mixed with
chalk, form a white one.
Lime compounds have the serious objection of acting as very rapid and
powerful fluxes, so that when clays containing them are heated
sufficiently to start partial fusion, a very slight additional rise in
temperature may easily reduce the whole to a shapeless, slag-like mass.
Magnesia compounds act much more slowly in this respect and so are less
harmful.
_Gypsum_--a calcium sulphate--occurs naturally in many sub-surface
clays, often in well-defined crystalline masses. It reduces the
heat-resisting power of the clays containing it and may, under some
conditions, rise to the surface of the articles made from the clay, in
the form of a white efflorescence or scum, such as is seen on some brick
walls.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account