The Nature of Animal LightHarvey, E. Newton (Edmund Newton)
Science
The Nature of Animal Light
Harvey, E. Newton (Edmund Newton)
Phosphorescence
PHOSPHORESCENCE AND FLUORESCENCE.--Although the word phosphorescence has
been used in a very loose way to indicate all kinds of luminescence, and
particularly that of phosphorus or of luminous animals, to the physicist
it has a very definite meaning, namely, the absorption of radiant energy
by substances which afterwards give this off as light. Phosphorescence
does not strictly apply to the light of white phosphorus. If the radiant
energy is light (visible or ultra-violet) we speak of
_photoluminescence_, if cathode rays we have _cathodoluminescence_, if
anode rays, _anodoluminescence_, and if X-rays (Röntgen rays) we have
_radioluminescence_. Inasmuch as the α, β, and γ rays of radium
correspond to the anode, cathode, and X-rays, respectively, radium
radiation also produces luminescence in many kinds of material. If the
material gives off the light only during the time it is radiated we
speak of fluorescence; if the light persists we speak of
phosphorescence. The distinction is perhaps a purely arbitrary one, as
there are a great many substances which give off light for only a
fraction of a second (1/5000 sec. in some cases) after being illuminated
(_photoluminescence_). Some substances also, which fluoresce at ordinary
temperatures, will phosphoresce at low temperatures. Phosphorescence is
exhibited chiefly by solids, fluorescence also by liquids and vapors.
Special means must be used to observe a phosphorescence of short
duration. E. Becquerel has devised an apparatus for doing this, a
_phosphoroscope_. It consists of revolving disks with holes in them
between which the object to be examined is placed. The holes are so
arranged that the object is first illuminated and then completely cut
off from light. The observer looking at it through another hole sees it
at the moment it is not illuminated and can thus tell if it is
phosphorescing. By determining the rate of revolution of the disks it is
easy to calculate how long the phosphorescence persists.
While relatively few solids phosphoresce after exposure to light at
ordinary temperature a large number of these acquire the property at the
temperature of liquid air. Included in the list are such biological
products as urea, salicylic acid, starch, glue and egg shells. The
temperature also affects the wave-length and hence the color of the
light given off. Usually the higher the temperature the shorter the
wave-length, but in the case of some bodies (SrS) the wave-lengths
become longer at the higher temperature.
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