The Nature of Animal LightHarvey, E. Newton (Edmund Newton)
Science
The Nature of Animal Light
Harvey, E. Newton (Edmund Newton)
Phosphorescence
The best known cases of phosphorescence which occur at room temperature
and the group to which the word phosphorescence is commonly applied, are
those of the alkaline earth sulphides (BaS, CaS, SrS) and ZnS. An
Italian, Vicenzo Cascariolo, is said to have discovered the Bologna
stone (BaSO_{4}) which, by calcination with charcoal, gave an impure
phosphorescent BaS or _lapis solaris_. Canton's phosphorus (CaS) was
later prepared "by heating a mixture of three parts of sifted calcined
oyster shells with one part of sulphur to an intense heat for one hour."
Hulme spoke of it as the "light magnet of Canton," because of its power
of attracting and absorbing light. The pure sulphides do not show this
property. Only if small amounts of some other metal such as Cu, Pb, Ag,
Zn, Sb, Ni, Bi, or Mn are present, will the sulphide phosphoresce. One
part of impurity in a million is often sufficient. Such mixtures,
together with a flux of Na_{2}SO_{4}, Li_{3}(PO_{4})_{2} or some other
fusible salt constitute a "phosphor." A "phosphor" is in reality an
example of a solid solution and is the basis of some kinds of luminous
paints.
The intensity and duration of a phosphorescent light depend chiefly on
the nature of the exciting rays, the color chiefly on the impurity
present but the alkaline earth metal also exerts an influence. Rise in
temperature increases the intensity but diminishes the duration, so that
the total amount of light emitted is about constant at different
temperatures.
The spectrum of most phosphorescent substances is made up of one or more
continuous bands having _maxima_ at different wave-lengths. In the light
incident on a phosphorescent substance are also bands of light rays
which are absorbed and whose wave-lengths are more efficient than others
in stimulating phosphorescence. These bands in the phosphorescent light
are usually of longer wave-length than those in the light which excites
the phosphorescence. This fact is known as Stokes' Law, but it has been
found not to be universally true. Curiously enough, red and infra-red
rays have the power of annulling phosphorescence after a momentary
increase in brightness and phosphorescing materials have been used to
determine if infra-red rays are given off in the light of the firefly.
Ives (1910) showed that infra-red radiation had no power of quenching
the light of the firefly as it does the phosphorescent light of Sidot
blende (ZnS), one fact tending to show that the firefly's light is not
due to phosphorescence. Fig. 3 is a reproduction of a photograph of the
phosphorescence spectrum of ZnS.
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