The Nature of Animal LightHarvey, E. Newton (Edmund Newton)
Science
The Nature of Animal Light
Harvey, E. Newton (Edmund Newton)
Phosphorescence
5. Oxidation in ozone. (Many organic substances.)
6. Oxidation in acid permanganate. (Pyrogallol.)
7. Oxidation in persulfates and perborates. (Formaldehyde,
paraformaldehyde.)
8. Oxidation in perchlorates, periodates, and perbromates. (Palmitic
acid.)
9. Combination of 2 and 4. (Many organic substances.)
10. Combination of 3 and 4. (Many organic substances.)
11. Oxidation with H_{2}O_{2} and hæmoglobin or vegetable oxidases.
(Pyrogallol, gallic acid, lophin, esculin.)
12. Oxidation with H_{2}O_{2} and MnO_{2}, Fe_{2}Fe(CN)_{6} Mn(OH)_{2} +
Mn(OH)_{3} Ag_{2}O, chromium oxide, cobalt oxide. (Pyrogallol.)
13. Oxidation with H_{2}O_{2} and ferrocyanides, chromates, bichromates,
permanganates, Fe salts, and Cr salts. (Pyrogallol, esculin.)
14. Oxidation with H_{2}O_{2} and collodial Ag. Pt. Pd. Au.
(Pyrogallol.)
The spectrum of chemiluminescent reactions has been described in a few
instances as continuous but no definite measurements of its extent have
been made. Radziszewski (1880) found the light of lophin oxidized in
alcoholic caustic alkali, examined with a two-prism spectroscope, to
give a continuous spectrum, brightest at _E_, with the red and violet
ends lacking. Trautz (1905, p. 101) states that the
pyrogallol-formaldehyde-Na_{2}CO_{3}-H_{2}O_{2} reaction gives a
continuous spectrum from the red to the blue green with maximum
brightness in the orange. Weiser (1918 _a_) has studied the spectra of
some chemiluminescent reactions by photographing the light behind a
series of color screens. He finds also that the spectra are short, with
maximum intensity in various regions. Thus, _amarin_ oxidized by
chlorine or bromine, extends from the yellow to greenish blue with a
maximum in the green while _phosphorus_, dissolved in glacial acetic
acid and oxidized with H_{2}O_{2}, luminesces from yellow green to
violet.
The spectra of luminous animals are quite similar to those of
chemiluminescent reactions. Moreover, as we have seen, chemiluminescence
is essentially an oxyluminescence, since oxygen is necessary for the
reaction. All luminous animals also require oxygen for light production.
Therefore, bioluminescence and chemiluminescence are similar phenomena
and they differ from all the other forms of luminescence which we have
considered. The light from luminous animals is due to the oxidation of
some substance produced in their cells, and when we can write the
structural formula of this photogenic substance and tell how the
oxidation proceeds, the problem of light production in animals will be
solved.
CHAPTER III
PHYSICAL NATURE OF ANIMAL LIGHT
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