The nature of the physical worldEddington, Arthur Stanley, Sir
Philosophy
The nature of the physical world
Eddington, Arthur Stanley, Sir
Physics -- Philosophy; Science -- Philosophy
Perhaps you may think that an extended stormy area ought to represent
diffused matter in contrast to a concentrated particle. That
is not Schrödinger’s theory. The spreading is not a spreading of
density; it is an indeterminacy of position, or a wider distribution
of the probability that the particle lies within particular limits of
position. Thus if we come across Schrödinger waves uniformly filling a
vessel, the interpretation is not that the vessel is filled with matter
of uniform density, but that it contains one particle which is equally
likely to be anywhere.
The first great success of this theory was in representing the emission
of light from a hydrogen atom—a problem far outside the scope of
classical theory. The hydrogen atom consists of a proton and electron
which must be translated into their counterparts in the sub-aether. We
are not interested in what the proton is doing, so we do not trouble
about its representation by waves; what we want from it is its field
of force, that is to say, the spurious which it provides in the
equation of wave-propagation for the electron. The waves travelling
in accordance with this equation constitute Schrödinger’s equivalent
for the electron; and any solution of the equation will correspond to
some possible state of the hydrogen atom. Now it turns out that (paying
attention to the obvious physical limitation that the waves must not
anywhere be of infinite amplitude) solutions of this wave-equation
only exist for waves with particular frequencies. Thus in a hydrogen
atom the sub-aethereal waves are limited to a particular discrete
[Pg 215]
series of frequencies. Remembering that a frequency in the sub-aether
means an energy in gross experience, the atom will accordingly have
a discrete series of possible energies. It is found that this series
of energies is precisely the same as that assigned by Bohr from his
rules of quantisation (p. 191). It is a considerable advance to
have determined these energies by a wave-theory instead of by an
inexplicable mathematical rule. Further, when applied to more complex
atoms Schrödinger’s theory succeeds on those points where the Bohr
model breaks down; it always gives the right number of energies or
“orbits” to provide one orbit jump for each observed spectral line.
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