The origin and development of the atomic theoryShipley, Maynard
History
The origin and development of the atomic theory
Shipley, Maynard
Atomic theory
But there is also a law of _multiple proportions_. It is
found that when one element forms more than one compound with a
second element, the quantities of the first element which combine
with the combining weight of the second element are always simple
multiples--never fractions--of the combining weight of the first
element.
We have seen that the _atomic_ weight of oxygen is 16--i.e., 16
times heavier than the lightest element, hydrogen, which is therefore
(on the relative scale of atomic weights) 1. But the _combining_
weight of oxygen is 8--i.e., eight _parts_ of oxygen will combine
with so many parts (combining weight) of some other element. Suppose
we take for example nitrogen. Now the _combining_ weight of
nitrogen is 14, and its _atomic_ weight is also 14. Fourteen parts
of nitrogen will combine therefore with eight parts of oxygen. But
fourteen parts of nitrogen will also combine with four simple multiples
of eight parts of oxygen, forming in all five different compound
substances. For example:
14 parts of nitrogen combine with 16 or 2x8 parts of oxygen.
14 parts of nitrogen combine with 24 or 3x8 parts of oxygen.
14 parts of nitrogen combine with 32 or 4x8 parts of oxygen.
14 parts of nitrogen combine with 40 or 5x8 parts of oxygen.
John Dalton advanced a theory satisfactorily to explain why in
successive compounds the amount of oxygen goes up in jumps, and why
this jump in each case is equivalent to the combining weight of oxygen.
The regular jumps in the case of the five nitrogen compounds simply
mean that one more atom has entered, in each successive case, into
combination. These combining weights, as we have seen, simply represent
the relative weights of the various elements. “Atomic weight” is merely
the name given by Dalton to the relative combining weights of the
atoms. He had no information as to how many atoms actually combine in
making a compound, much less of the actual weight of the single atoms
of the elements.
Nor did he know _why_ atoms combine at all, in any proportions,
but, being a thorough-going Newtonian, both his physical theory and
his chemical theory have a common basis in Newton’s doctrine of
mutually repulsive atoms. If an element A unites with an element B, the
repulsion of the atoms of B from one another must tend, he thought, to
the formation of a binary compound. “Binary compounds must first be
formed, then ternary, and so on, till the repulsion of the atoms of B
refuses to admit any more.”[28]
While we have traveled quite a distance in atomic and chemical theory
since the days of John Dalton (1766-1844), it is to the everlasting
credit of this (at the time) obscure and poverty-stricken teacher
of mathematics and physics that he gave us, in 1808, “A new System
of Chemical Philosophy” which unites the atomic theory of modern
science, first advanced by his admirers and contemporaries, Baron J. J.
Berzelius (1779-1848) and Sir Humphrey Davy (1778-1829).
Public-domain text, read in full here on John Shaqi.
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