The Phase Rule and Its ApplicationsFindlay, Alexander
Science
The Phase Rule and Its Applications
Findlay, Alexander
Chemistry, Physical and theoretical; Phase rule and equilibrium; Solution (Chemistry)
Graphic Representation.--Hitherto the concentrations of the components have
been represented by means of rectangular co-ordinates, although the
numerical relationships have been expressed in two different ways. In the
one case, the concentration of the one component was expressed in terms of
a fixed amount of the other component. Thus, the solubility of a salt was
expressed by the number of grams of salt dissolved by 100 grams of water or
other solvent; and the numbers so obtained were measured along one of the
co-ordinates. The second co-ordinate was then employed to indicate the
change of another independent variable, _e.g._ temperature. In the other
case, the combined weights of the two components A and B were put equal to
unity, and the concentration of the one expressed as a fraction of the
whole amount. This method allows of the representation of the complete
series of concentrations, from pure A to pure B, and was employed, for
example, in the graphic representation of the freezing point curves.
Even in the case of three components rectangular co-ordinates can also be
employed, and, indeed, are the most convenient in those cases where the
behaviour of two of the components to one another is very different from
their behaviour to the third component; as, for example, in the case of two
salts and water. In these cases, the composition of the system can be
represented by measuring the amounts of each of the two components in a
given weight of the third, along two co-ordinates at right angles to one
another; and the change of the system with the temperature can then be
represented by a third axis at right angles to the first two. In those
cases, {236} however, where the three components behave in much the same
manner towards one another, the rectangular co-ordinates are not at all
suitable, and instead of these a _triangular diagram_ is employed. Various
methods have been proposed for the graphic representation of systems of
three components by means of a triangle, but only two of these have been
employed to any considerable extent; and a short description of these two
methods will therefore suffice.[317]
[Illustration: FIG. 80.]
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