What is it that determines whether or not an energy-transformation will
occur? It is the condition that a difference of the intensity-factors
of the energy in different parts of a system exists. Water will
flow from a higher to a lower level, doing work as it flows, if
it is directed through a motor. Electricity will flow if there is
a difference of electrical potential. A chemical reaction will
occur if two substances before interacting possess greater chemical
potential than do the products which may possibly be formed during the
interaction. Coal and oxygen possess greater chemical potential than do
carbon dioxide and water, therefore they will combine, forming carbon
dioxide and water. Energy-transformations will therefore occur wherever
it is possible that differences of intensity or potential can become
abolished. The energy that may thus flow from a condition of high to a
condition of low potential, undergoing a transformation as it flows, is
the available energy of the system of bodies in which it is contained.
A closed vessel surrounded by an envelope impervious to heat, and
containing a mixture of oxygen and hydrogen, is an isolated system
containing available energy. Let the mixture be fired by an electric
spark, and heat is evolved. The total energy of the system is unaltered
in amount, but the available energy has disappeared, since the heated
water vapour is incapable of undergoing further transformations while
it forms part of its isolated system.[12]
[12] It is really necessary to lay stress on the distinction between
available and unavailable energy, as it is one which many biologists
appear to ignore. Thus, a popular book on the making of the earth
attempts to argue that essential distinctions between living and
inorganic matter are non-existent. One of these distinctions is that
organisms absorb energy, and this author points to the absorption
of “latent heat” by melting ice as an example of the absorption of
energy in a purely physical process. Consider a system consisting
of a block of ice and a small steam boiler. We can obtain work
from this by the melting of the ice--that is, its “absorption of
latent heat.” The system, ice at 0° C. + steam at 100° C., possesses
available energy, but the system, melted ice + condensed steam, both
at the same temperature, contains none. The molecules of water at
0° C. “absorb energy,” that is to say, their kinetic energy becomes
greater, but their available energy in the system has disappeared. In
saying that the organism absorbs energy, we mean, of course, that it
accumulates available energy, that is, the power of producing physical
transformations. (See further, appendix, p. 366.)
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