The Poetry of Science; or, Studies of the Physical Phenomena of NatureHunt, Robert
Philosophy
The Poetry of Science; or, Studies of the Physical Phenomena of Nature
Hunt, Robert
Physics; Science
[205] _On certain combinations of a new acid, formed of Azote, Sulphur,
and Oxygen_; by J. Pelouze. Translated from Annales de Chimie, vol.
xvi., for Scientific Memoirs, vol. i. p. 470. _Some ideas of a new
force acting in the combinations of Organic Compounds_, by Berzelius:
Annales de Chimie, vol. lxi. The conclusion come to by this eminent
chemist is expressed in the following translation:--“This new power,
hitherto unknown, is common both in organic and inorganic nature.
I do not believe that it is a power which is entirely independent
of the electro-chemical affinities of the substance. I believe, on
the contrary, that it is merely a new form of it; but so long as we
do not see their connection and mutual dependence, it will be more
convenient to describe it by a separate name. I shall, therefore, call
it _catalytic power_: I shall also call _catalysis_, the decomposition
of bodies by this force--in the same way as the decomposition of bodies
by chemical affinity is termed analysis.”
[206] Berzelius: _Annales de Chimie_, vol. lxi.
[207] _On Transformations produced by Catalytic Bodies_: by Lyon
Playfair, Esq.; Phil. Mag., vol. xxxi. p. 191, 1847.--“Facts have been
brought forward to show that there is at least as much probability in
the view that the catalytic force is merely a modified form of chemical
affinity exerted under peculiar conditions, as there is in ascribing
it to an unknown power, or to the communication of an intestine motion
to the atoms of a complex molecule. Numerous cases have been cited,
in which the action results when the assisting or catalytic body is
not in a state of change; and attempts have been made to prove, by new
experiments, that the catalytic power exercises its peculiar power by
acting in the same direction as the body decomposing, or entering into
union, but under conditions in which its own affinity cannot always be
gratified.”
[208] Consult Graham’s Chemistry, _On Combining Proportions_.
[209] _Memoir on Atomic Volume and Specific Gravity._ Messrs. Lyon
Playfair and Joule.--Philosophical Magazine, vol. xxvii. p. 453, or
Transactions of Chemical Society of London. _Observations_ on the
above, by Professor de Marignac.--Bibliothèque Universelle, Feb. 1846.
_On the Relation of the Volumes of bodies in the solid state, to their
equivalents, or atomic weights_: by Professor Otto. _Studies on the
connection between the atomic weights, crystalline form, and density
of bodies_: by M. Filhol. Translated for the Cavendish Society, and
published in their Chemical Reports and Memoirs.
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