The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
Assuming we commence by making up our stock solution of acid by adding
100 parts of water to 1 part of pure acid, this gives us a mixture of
1 to 100. For 1 gallon of pure latex it would be necessary to add
one-tenth of its volume of the above mixture--_i.e._, 16 ozs.
Suppose we take a gallon of pure latex and add a gallon of water, we
now have 2 gallons of so-called latex. But we still have only 1 gallon
of real latex present in the diluted latex, and it is only necessary
to add sufficient acid to coagulate this gallon--_i.e._, 16 ozs.
Further, if 1 gallon of latex be diluted with 2, 3, or even 4 gallons
of water it is still only necessary to add 16 ozs. of the acid
mixture.
At dilutions beyond this limit, however, it is necessary to add a
little more acid to obtain complete coagulation.
In the process of preparing sheet rubber it is very necessary to see that
the minimum quantity of acid is used, otherwise visible defects are caused.
But in coagulating latex intended for preparing crepe, where the rubber
undergoes protracted washing on the machines, the presence of a slight
excess of acid in coagulation is not calculated to cause any deterioration
in the quality of the rubber. Advantage must not be taken of this statement
to argue that more than a slight excess may be used without injury to the
rubber, as it can be shown that the use of a large excess of acid results
in an inferior rubber.
QUANTITIES NECESSARY FOR MODERN REQUIREMENTS.--It may be commended to the
notice of the beginner that any further experimental work as to the
quantity of acetic acid necessary for complete coagulation would only
involve a waste of time and energy.
The general figure given in a preceding paragraph (1 part pure acid to
1,000 parts of latex) may be accepted as the rough basis for working. In
modern practice, however, undiluted latex is usually diluted to a standard
which may vary on different estates from 1-1/4 lbs. to 1-1/2 lbs. dry
rubber per gallon.
Latices of these strengths can be coagulated at a ratio of 1 part pure acid
to 1,200 parts of standardised latex; and this quantity need not be
exceeded, except in cases where an appreciable amount of some
anti-coagulant is present in the latex. The proportion may then be raised
to 1 in 1,000.
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