The Preparation of Plantation RubberMorgan, Sidney
Science
The Preparation of Plantation Rubber
Morgan, Sidney
Rubber
USE OF SODIUM BISULPHITE.--Some few years ago a demand for pale crepe
rubbers sprang up, and this demand has been maintained. The total quantity
of pale rubber put on the market previously could only have amounted to
very little, and that little was obtained by luck and various tricks in
manipulation. It must be premised that if coagulation is allowed to take
place, either naturally or with the aid of acetic acid, the resulting
rubber will almost inevitably oxidise on the surface, except in the cases
of very dilute or young latices. Even supposing that this darkening of the
surface does not take place in the wet stage, it is often found that a
rubber expected to dry to a pale colour does not fulfil expectations, and a
dull neutral shade results. This darkening of crepe rubber may be
attributed to a slow process of oxidation, which continues until the rubber
is dry. From these remarks it will be seen that the process of oxidation is
a natural one, and that any pale rubber formerly shipped was the outcome of
circumstances outside the control of the estate, except in such cases where
boiling of the coagulum, etc., was resorted to. The fact that one rubber
happened to be a shade darker than another was absolutely no criterion as
to the value of the rubber, but apparently the market thought, and still
thinks, otherwise, although the actual necessities of manufacturers for a
pale crepe to be employed in special processes must be comparatively small.
The prevention of this natural oxidation was a problem which exercised the
minds of all responsible for the preparation of pale rubbers, and much time
and thought were expended upon it. Various theories were propounded, and
the chief conclusion arrived at was that the darkening of rubber was to be
prevented by excluding all the light possible from the drying houses. To
this end windows were to be kept shut, or else they were provided with
ruby-coloured glass, which incidentally kept out the air. In spite of these
precautions, little success attended the expenditure of so much energy and
thought. It was absolutely necessary that some chemical agent should be
discovered which would make the preparation of pale crepe possible for any
estate. This chemical would have to fulfil several requirements before it
could become popular:
1. It must be a simple substance capable of being easily handled.
2. It must be very soluble, so that solutions could easily be made up
by inexpert workers.
3. It must be cheap.
4. It must be quite innocent of any harmful effect upon the quality of
the rubber.
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