The Principles of Biology, Volume 1 (of 2)Spencer, Herbert
Science
The Principles of Biology, Volume 1 (of 2)
Spencer, Herbert
Biology
§ 3. Passing now to the substances which contain three of these chief
organic elements, we have first to note that along with the greater atomic
weight which mostly accompanies their increased complexity, there is, on
the average, a further marked decrease of molecular mobility. Scarcely any
of them maintain a gaseous state at ordinary temperatures. One class of
them only, the alcohols and their derivatives, evaporate under the usual
atmospheric pressure; but not rapidly unless heated. The fixed oils, though
they show that molecular mobility implied by an habitually liquid state,
show this in a lower degree than the alcoholic compounds; and they cannot
be reduced to the gaseous state without decomposition. In their allies, the
fats, which are solid unless heated, the loss of molecular mobility is
still more marked. And throughout the whole series of the fatty acids, in
which to a fixed proportion of oxygen there are successively added higher
equimultiples of carbon and hydrogen, we see how the molecular mobility
decreases with the increasing sizes of the molecules. In the amylaceous and
sugar-group of compounds, solidity is the habitual state: such of them as
can assume the liquid form, doing so only when heated to 300° or 400° F.;
and decomposing when further heated, rather than become gaseous. Resins and
gums exhibit general physical properties of like character and meaning.
In chemical stability these triatomic compounds, considered as a group, are
in a marked degree below the diatomic ones. The various sugars and kindred
bodies, decompose at no very high temperatures. The oils and fats also are
readily carbonized by heat. Resinous and gummy substances are easily made
to render up some of their constituents. And the alcohols, with their
allies, have no great power of resisting decomposition. These bodies,
formed by the union of oxygen, hydrogen, and carbon, are also, as a class,
chemically inactive. Formic and acetic are doubtless energetic acids; but
the higher members of the fatty-acid series are easily separated from the
bases with which they combine. Saccharic acid, too, is an acid of
considerable power; and sundry of the vegetable acids possess a certain
activity, though an activity far less than that of the mineral acids. But
throughout the rest of the group, there is shown but a small tendency to
combine with other bodies; and such combinations as are formed have usually
little permanence.
The phenomena of isomerism and polymerism are of frequent occurrence in
these triatomic compounds. Starch and dextrine are probably polymeric.
Fruit-sugar and grape-sugar, mannite and sorbite, cane-sugar and
milk-sugar, are isomeric. Sundry of the vegetal acids exhibit similar
modifications. And among the resins and gums, with their derivatives,
molecular re-arrangements of this kind are not uncommon.
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