The Principles of Biology, Volume 1 (of 2)Spencer, Herbert
Science
The Principles of Biology, Volume 1 (of 2)
Spencer, Herbert
Biology
§ 2. Among the diatomic combinations of the three elements, hydrogen,
nitrogen and oxygen, we find a molecular mobility much less than that of
these elements themselves; at the same time that it is much greater than
that of diatomic compounds in general. Of the two products formed by the
union of oxygen with carbon, the first, called carbonic oxide, which
contains one atom[3] of carbon to one of oxygen (expressed by the symbol
CO) is a gas condensible only with great difficulty; and the second,
carbonic acid, containing an additional atom of oxygen (CO_{2}) assumes a
liquid form also only under a pressure of about forty atmospheres. The
several compounds of oxygen with nitrogen, present us with an instructive
gradation. Nitrous oxide (N_{2}O), is a gas condensible only under a
pressure of some fifty atmospheres; nitric oxide (NO) is a gas which
although it has been liquefied does not condense under a pressure of 270
atmospheres at 46.4° F. (8° C.): the molecular mobility remaining
undiminished in consequence of the volume of the united gases remaining
unchanged. Nitrogen trioxide (N_{2}O_{3}) is gaseous at ordinary
temperatures, but condenses into a very volatile liquid at the zero of
Fahrenheit; nitrogen tetroxide (N_{2}O_{4}) is liquid at ordinary
temperatures and becomes solid at the zero of Fahrenheit; while nitrogen
pentoxide (N_{2}O_{5}) may be obtained in crystals which melt at 85° and
boil at 113°. In this series we see, though not with complete uniformity, a
decrease of molecular mobility as the weights of the compound molecules are
increased. The hydro-carbons illustrate the same general truth still
better. One series of them will suffice. Marsh gas (CH_{4}) is gaseous
except under great pressure and at very low temperatures. Olefiant gas
(C_{2}H_{4}) and ethane (C_{2}H_{6}) may be readily liquefied by pressure.
Propane (C_{3}H_{8}) becomes liquid without pressure at the zero of
Fahrenheit. Hexane (C_{5}H_{12}) is a liquid which boils at 160°. And the
successively higher multiples, heptane (C_{7}H_{16}), octane (C_{8}H_{18}),
and nonane (C_{9}H_{20}) are liquids which boil respectively at 210°, 257°,
and 302°. Pentadecan (C_{15}H_{32}) is a liquid which boils at 270°, while
paraffin-wax, which contains the still higher multiples, is solid. There
are three compounds of hydrogen and nitrogen that have been obtained in a
free state--ammonia (NH_{3}) is gaseous, but liquefiable by pressure, or by
reducing its temperature to -40° F., and it solidifies at -112° F.;
hydrazine (NH_{2}--NH_{2}) is liquid at ordinary temperatures, but
hydrozoic acid (N_{3}H) has so far only been obtained in the form of a
highly explosive gas. In cyanogen, which is composed of carbon and
nitrogen, (CN)_{2}, we have a gas that becomes liquid at a pressure of four
atmospheres and solid at -30° F. And in paracyanogen, formed of the same
proportions of these elements in higher multiples, we have a solid which
does not fuse or volatilize at ordinary temperatures.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account