The Principles of Biology, Volume 1 (of 2)Spencer, Herbert
Science
The Principles of Biology, Volume 1 (of 2)
Spencer, Herbert
Biology
Lastly, in the most
important member of this group, water (H_{2}O), we have a compound of two
difficultly-condensible gases which assumes both the fluid state and the
solid state within ordinary ranges of temperature; while its molecular
mobility is still such that its fluid or solid masses are continually
passing into the form of vapour, though not with great rapidity until the
temperature is raised to 212°.
Considering them chemically, it is to be remarked of these diatomic
compounds of the four chief organic elements, that they are, on the
average, less stable than diatomic compounds in general. Water, carbonic
oxide, and carbonic acid, are, it is true, difficult to decompose. But
omitting these, the usual strength of union among the elements of the
above-named substances is low considering the simplicity of the substances.
With the exception of acetylene and possibly marsh gas, the various
hydro-carbons are not producible by directly combining their elements; and
the elements of most of them are readily separable by heat without the aid
of any antagonistic affinity. Nitrogen and hydrogen do not unite with each
other immediately save under very exceptional circumstances; and the
ammonia which results from their union, though it resists heat, yields to
the electric spark. Cyanogen is stable: not being resolved into its
components below a bright red heat. Much less stable, however, are several
of the oxides of nitrogen. Nitrous oxide, it is true, does not yield up its
elements below a red heat; but nitrogen tetroxide cannot exist if water be
added to it; nitrous acid is decomposed by water; and nitric acid not only
readily parts with its oxygen to many metals, but when anhydrous,
spontaneously decomposes. Here it will be well to note, as having a bearing
on what is to follow, how characteristic of most nitrogenous compounds is
this special instability. In all the familiar cases of sudden and violent
decomposition, the change is due to the presence of nitrogen. The explosion
of gunpowder results from the readiness with which the nitrogen contained
in the nitrate of potash, yields up the oxygen combined with it. The
explosion of gun-cotton, which also contains nitrogen, is a substantially
parallel phenomenon. The various fulminating salts are all formed by the
union with metals of a certain nitrogenous acid called fulminic acid; which
is so unstable that it cannot be obtained in a separate state.
Explosiveness is a property of nitro-mannite, and also of nitro-glycerin.
Iodide of nitrogen detonates on the slightest touch, and often without any
assignable cause. And the bodies which explode with the most tremendous
violence of any known, are the chloride of nitrogen (NCl_{3}) and hydrazoic
acid (N_{3}H). Thus these easy and rapid decompositions, due to the
chemical indifference of nitrogen, are characteristic. When we come
hereafter to observe the part which nitrogen plays in organic actions, we
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