The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
But he did not make more accurate experiments, which would
have shown the relative quantities of the component parts in water,
and which would have determined its complex nature with certainty.
Although his experiments were the first, and although the conclusion
he drew from them was true, yet such novel ideas as the complex nature
of water are not easily recognised so long as there is no series of
researches which entirely and indubitably proves the truth of such a
conclusion. The fundamental experiments which proved the complexity
of water by the method of synthesis, and of its formation from other
substances, were made in 1789 by Monge, Lavoisier, Fourcroy, and
Vauquelin. They obtained four ounces of water by burning hydrogen,
and found that water consists of 15 parts of hydrogen and 85 parts of
oxygen. It was also proved that the weight of water formed was equal
to the sum of the weights of the component parts entering into its
composition; consequently, water contains all the matter entering into
oxygen and hydrogen. The complexity of water was proved in this manner
by a method of synthesis. But we will turn to its analysis--_i.e._ to
its decomposition into its component parts. The analysis may be more or
less complete. Either both component parts may be obtained in a separate
state, or else only one is separated and the other is converted into a
new compound in which its amount may be determined by weighing. This
will be a reaction of substitution, such as is often taken advantage of
for analysis. The first analysis of water was thus conducted in 1784
by Lavoisier and Meusnier. The apparatus they arranged consisted of a
glass retort containing water previously purified, and of which the
weight had been determined. The neck of the retort was inserted into
a porcelain tube, placed inside an oven, and heated to a red heat by
charcoal. Iron filings, which decompose water at a red heat, were placed
inside this tube. The end of the tube was connected with a worm, for
condensing any water which might pass through the tube undecomposed.
This condensed water was collected in a separate flask. The gas formed
by the decomposition was collected over water in a bell jar. The aqueous
vapour in passing over the red-hot iron was decomposed, and a gas was
formed from it whose weight could be determined from its volume, its
density being known. Besides the water which passed through the tube
unaltered, a certain quantity of water disappeared in the experiment,
and this quantity, in the experiments of Lavoisier and Meusnier, was
equal to the weight of gas which was collected in the bell jar plus the
increase in weight of the iron filings. Hence the water was decomposed
into a gas, which was collected in the bell jar, and a substance, which
combined with the iron; consequently, it is composed of these two
component parts. This was the first analysis of water ever made; but
here only one (and not both) of the gaseous component parts of water was
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