The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
collected separately. Both the component parts of water can, however,
be simultaneously obtained in a free state. For this purpose the
decomposition is brought about by a galvanic current or by heat, as we
shall learn directly.[1]
[1] The first experiments of the synthesis and decomposition of water
did not afford, however, an entirely convincing proof that water
was composed of hydrogen and oxygen only. Davy, who investigated
the decomposition of water by the galvanic current, thought for a
long time that, besides the gases, an acid and alkali were also
obtained. He was only convinced of the fact that water contains
nothing but hydrogen and oxygen by a long series of researches,
which showed him that the appearance of an acid and alkali in the
decomposition of water proceeds from the presence of impurities
(especially from the presence of ammonium nitrate) in water. A
final comprehension of the composition of water is obtained from
the accurate determination of the quantities of the component
parts which enter into its composition. It will be seen from
this how many data are necessary for proving the composition of
water--that is, of the transformations of which it is capable.
What has been said of water refers to all other compounds; the
investigation of each one, the entire proof of its composition,
can only be obtained by the accumulation of a large mass of data
referring to it.
Water is a bad conductor of electricity--that is, pure water does not
transmit a feeble current; but if any salt or acid be dissolved in it,
then its conductivity increases, and _on the passage of a current_
through acidified water _it is decomposed_ into its component parts.
Some sulphuric acid is generally added to the water. By immersing
platinum plates (electrodes) in this water (platinum is chosen because
it is not acted on by acids, whilst many other metals are chemically
acted on by acids), and connecting them with a galvanic battery, it
will be observed that bubbles of gas appear on these plates. The gas
which separates is called _detonating gas_,[2] because, on ignition,
it very easily explodes.[3] What takes place is as follows:--First,
the water, by the action of the current, is decomposed into two gases.
The mixture of these gases forms detonating gas. When detonating gas
is brought into contact with an incandescent substance--for instance,
a lighted taper--the gases re-combine, forming water, the combination
being accompanied by a great evolution of heat, and therefore the vapour
of the water formed expands considerably, which it does very rapidly,
and as a consequence, an explosion takes place--that is, sound and
increase of pressure, and atmospheric disturbance, as in the explosion
of gunpowder.
[2] This gas is collected in a voltameter.
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