The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[3] In order to observe this explosion without the slightest danger,
it is best to proceed in the following manner. Some soapy water is
prepared, so that it easily forms soap bubbles, and it is poured
into an iron trough. In this water, the end of a gas-conducting
tube is immersed. This tube is connected with any suitable
apparatus, in which detonating gas is evolved. Soap bubbles,
full of this gas, are then formed. If the apparatus in which the
gas is produced be then removed (otherwise the explosion might
travel into the interior of the apparatus), and a lighted taper be
brought to the soap bubbles, a very sharp explosion takes place.
The bubbles should be small to avoid any danger; ten, each about
the size of a pea, suffice to give a sharp report, like a pistol
shot.
In order to discover what gases are obtained by the decomposition of
water, the gases which separate at each electrode must be collected
separately. For this purpose a V-shaped tube is taken; one of its ends
is open and the other fused up. A platinum wire, terminating inside
the tube in a plate, is fused into the closed end; the closed end is
entirely filled with water[4] acidified with sulphuric acid, and another
platinum wire, terminating in a plate, is immersed in the open end. If
a current from a galvanic battery be now passed through the wires an
evolution of gases will be observed, and the gas which is obtained in
the open branch passes into the air, while that in the closed branch
accumulates above the water. As this gas accumulates it displaces the
water, which continues to descend in the closed and ascend into the open
branch of the tubes. When the water, in this way, reaches the top of the
open end, the passage of the current is stopped, and the gas which was
evolved from one of the electrodes only is obtained in the apparatus.
By this means it is easy to prove that a particular gas appears at each
electrode. If the closed end be connected with the negative pole--_i.e._
with that joined to the zinc--then the gas collected in the apparatus
is capable of burning. This may be demonstrated by the following
experiment:--The bent tube is taken off the stand, and its open end
stopped up with the thumb and inclined in such a manner that the gas
passes from the closed to the open end. It will then be found, on
applying a lighted lamp or taper, that the gas burns. This combustible
gas is _hydrogen_. If the same experiment be carried on with a current
passing in the opposite direction--that is, if the closed end be joined
up with the positive pole (_i.e._ with the carbon, copper, or platinum),
then the gas which is evolved from it does not itself burn, but it
supports combustion very vigorously, so that a smouldering taper in it
immediately bursts into flame. This gas, which is collected at the anode
or positive pole, is _oxygen_, which is obtained, as we saw before (in
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