The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
figures, falls to -115° (Dewar). Even the evaporation of liquids
of common occurrence, under low pressures easily attainable with
an air-pump, may produce low temperatures, which may be again
taken advantage of for obtaining still lower temperatures. Water
boiling in a vacuum becomes cold, and under a pressure of less
than 4·5 mm. it freezes, because its tension at 0° is 4·5 mm.
A sufficiently low temperature may be obtained by forcing fine
streams of air through common ether, or liquid carbon bisulphide,
CS_{2}, or methyl chloride, CH_{3}Cl, and other similar volatile
liquids. In the adjoining table are given, for certain gases, (1)
the number of atmospheres necessary for their liquefaction at
15°, and (2) the boiling points of the resultant liquids under a
pressure of 760 mm.
C_{2}H_{4} N_{2}O CO_{2}, H_{2}S
(1) 42 31 52 10
(2) -103° -92° -80° -74°
AsH_{3}, NH_{3} HCl CH_{3}Cl C_{2}N_{2} SO_{2}
(1) 8 7 25 4 4 3
(2) -58° -38° -35° -24° -21° -10°
[28] Natterer's determinations (1851-1854), together with Amagat's
results (1880-1888), show that the compressibility of hydrogen,
under high pressures, may be expressed by the following figures:--
_p_ = 1 100 1000 2500
_v_ = 1 0·0107 0·0019 0·0013
_pv_ = 1 1·07 1·9 3·25
_s_ = 0·11 10·3 58 85
where _p_ = the pressure in metres of mercury, _v_ = the volume,
if the volume taken under a pressure of 1 metre = 1, and _s_
the weight of a litre of hydrogen at 20° in grams. If hydrogen
followed Mariotte's law, then under a pressure of 2,500 metres,
one litre would contain not 85, but 265 grams. It is evident
from the above figures that the weight of a litre of the gas
approaches a limit as the pressure increases, which is doubtless
the density of the gas when liquefied, and therefore the weight
of a litre of liquid hydrogen will probably be near 100 grams
(density about 0·1, being less than that of all other liquids).
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