The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[42] This property of spongy platinum is made use of in the so-called
hydrogen cigar-lighter. It consists of a glass cylinder or
beaker, inside which there is a small lead stand (which is not
acted on by sulphuric acid), on which a piece of zinc is laid.
This zinc is covered by a bell, which is open at the bottom
and furnished with a cock at the top. Sulphuric acid is poured
into the space between the bell and the sides of the outer
glass cylinder, and will thus compress the gas in the bell. If
the cock of the cylinder be opened the gas will escape by it,
and will be replaced by the acid, which, coming into contact
with the zinc, evolves hydrogen, and it will escape through the
cock. If the cock be closed, then the hydrogen evolved will
increase the pressure of the gas in the bell, and thus again
force the acid into the space between the bell and the walls of
the outer cylinder. Thus the action of the acid on the zinc may
be stopped or started at will by opening or shutting the cock,
and consequently a stream of hydrogen may be always turned on.
Now, if a piece of spongy platinum be placed in this stream, the
hydrogen will take light, because the spongy platinum becomes
hot in condensing the hydrogen and inflames it. The considerable
rise in temperature of the platinum depends, among other things,
on the fact that the hydrogen condensed in its pores comes into
contact with previously absorbed and condensed atmospheric
oxygen, with which hydrogen combines with great facility in this
form. In this manner the hydrogen cigar-lighter gives a stream of
burning hydrogen when the cock is open. In order that it should
work regularly it is necessary that the spongy platinum should be
quite clean, and it is best enveloped in a thin sheet of platinum
foil, which protects it from dust. In any case, after some time
it will be necessary to clean the platinum, which may be easily
done by boiling it in nitric acid, which does not dissolve the
platinum, but clears it of all dirt. This imperfection has given
rise to several other forms, in which an electric spark is made
to pass before the orifice from which the hydrogen escapes. This
is arranged in such a manner that the zinc of a galvanic element
is immersed when the cock is turned, or a small coil giving a
spark is put into circuit on turning the hydrogen on.
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