The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Knowing the amount of oxygen in the
water formed, we also know the quantity of hydrogen contained in
it, and consequently we determine the composition of water by
weight. This is the essence of the determination. We will now
turn to certain particulars. In one neck of the three-necked
bottle a tube is placed dipping under mercury. This serves as
a safety-valve to prevent the pressure inside the apparatus
becoming too great from the rapid evolution of hydrogen. If the
pressure rose to any considerable extent, the current of gases
and vapours would be very rapid, and, as a consequence, the
hydrogen would not be perfectly purified, or the water entirely
absorbed in the tubes placed for this purpose. In the third neck
of the Woulfe's bottle is a tube conducting the hydrogen to the
purifying apparatus, consisting of eight [U] tubes, destined
for the purification and testing of the hydrogen. The hydrogen,
evolved by zinc and sulphuric acid, is purified by passing it
first through a tube full of pieces of glass moistened with a
solution of lead nitrate next through silver sulphate; the lead
nitrate retains sulphurette hydrogen, and arseniuretted hydrogen
is retained by the tube with silver sulphate. Caustic potash in
the next [U] tube retains any acid which might come over. The
two following tubes are filled with lumps of dry caustic potash
in order to absorb any carbonic anhydride and moisture which the
hydrogen might contain. The next two tubes, to remove the last
traces of moisture, are filled with phosphoric anhydride, mixed
with lumps of pumice-stone. They are immersed in a freezing
mixture. The small [U] tube contains hygroscopic substances,
and is weighed before the experiment: this is in order to know
whether the hydrogen passing through still retains any moisture.
If it does not, then the weight of this tube will not vary during
the whole experiment, but if the hydrogen evolved still retains
moisture, the tube will increase in weight. The copper oxide is
placed in the bulb, which, previous to the experiment, is dried
with the copper oxide for a long period of time. The air is then
exhausted from it, in order to weigh the oxide of copper in a
vacuum and to avoid the need of a correction for weighing in
air. The bulb is made of infusible glass, that it may be able to
withstand a lengthy (20 hours) exposure to a red heat without
changing in form. The weighed bulb is only connected with the
purifying apparatus after the hydrogen has passed through for
a long time, and after experiment has shown that the hydrogen
passing from the purifying apparatus is pure and does not
contain any air. On passing from the condensing bulb the gas and
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