The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
lighted in air cannot so well be introduced into the flask, because
it burns very rapidly and with a large flame in air. If a small lump
of metallic _sodium_ be put in a small cup made of lime,[25] melted,
and ignited,[26] it burns very feebly in air. But if burning sodium be
introduced into oxygen, the combustion is invigorated and is accompanied
by a brighter yellow flame. Metallic _magnesium_, which burns brightly
in air, continues to burn with still greater vigour in oxygen, forming
a white powder, which is a compound of magnesium with oxygen (magnesium
oxide; magnesia). A strip of _iron_ or steel does not burn in air, but
an iron wire or steel spring may be easily burnt in oxygen.[27] The
combustion of steel or iron in oxygen is not accompanied by a flame, but
sparks of oxide fly in all directions from the burning portions of the
iron.[28]
[22] Certain substances (with which we shall afterwards become
acquainted), however, ignite spontaneously in air; for example,
impure phosphuretted hydrogen, silicon hydride, zinc ethyl, and
pyrophorus (very finely divided iron, &c.)
[23] If so little heat is evolved that the adjacent parts are not
heated to the temperature of combustion, then combustion will
cease.
[24] The phosphorus must be dry; it is usually kept in water, as
it oxidises in air. It should be cut under water, as otherwise
the freshly-cut surface oxidises. It must be dried carefully and
quickly by wrapping it in blotting-paper. If damp, it splutters
on burning. A small piece should be taken, as otherwise the iron
spoon will melt. In this and the other experiments on combustion,
water should be poured over the bottom of the vessel containing
the oxygen, to prevent it from cracking. The cork closing
the vessel should not fit tightly, in order to allow for the
expansion of the gas due to the heat of the combustion.
[25] An iron cup will melt with sodium in oxygen.
[26] In order to rapidly heat the lime crucible containing the sodium,
it is heated in the flame of a blowpipe described in Chap. VIII.
[27] In order to burn a watch spring, a piece of tinder (or paper
soaked in a solution of nitre, and dried) is attached to one
end. The tinder is lighted, and the spring is then plunged into
the oxygen. The burning tinder heats the end of the spring, the
heated part burns, and in so doing heats the further portions of
the spring, which then burns completely if sufficient oxygen be
present.
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