The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[28] The sparks of rust are produced, owing to the fact that the volume
of the oxide of iron is nearly twice that of the volume of the
iron, and as the heat evolved is not sufficient to entirely melt
the oxide or the iron, the particles must be torn off and fly
about. Similar sparks are formed in the combustion of iron, in
other cases also. We saw the combustion of iron filings in the
Introduction. In the welding of iron small iron splinters fly off
in all directions and burn in the air, as is seen from the fact
that whilst flying through the air they remain red hot, and also
because, on cooling, they are seen to be no longer iron, but a
compound of it with oxygen. The same thing takes place when the
hammer of a gun strikes against the flint. Small scales of steel
are heated by the friction, and glow and burn in the air. The
combustion of iron is still better seen by taking it as a very
fine powder, such as is obtained by the decomposition of certain
of its compounds--for instance, by heating Prussian blue, or by
the reduction of its compounds with oxygen by hydrogen; when this
fine powder is strewn in air, it burns by itself, even without
being previously heated (it forms a pyrophorus). This obviously
depends on the fact that the powder of iron presents a larger
surface of contact with air than an equal weight in a compact
form.
[Illustration: FIG. 30.--Mode of burning a steel spring in oxygen.]
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