The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[29] The experiment may be conducted without the wires, if the hydrogen
be lighted in the orifice of an inverted cylinder, and at
the same time the cylinder be brought over the end of a
gas-conducting tube connected with a gas-holder containing
oxygen. Thomsen's method may be adopted for a lecture experiment.
Two glass tubes, with platinum ends, are passed through orifices,
about 1-1-1/2 centimetre apart, in a cork. One tube is connected
with a gas-holder containing oxygen, and the other with a
gas-holder full of hydrogen. Having turned on the gases, the
hydrogen is lighted, and a common lamp glass, tapering towards
the top, is placed over the cork. The hydrogen continues to burn
inside the lamp glass, at the expense of the oxygen. If the
current of oxygen be then decreased little by little, a point is
reached when, owing to the insufficient supply of oxygen, the
flame of the hydrogen increases in size, disappears for several
moments, and then reappears at the tube supplying the oxygen. If
the flow of oxygen be again increased, the flame reappears at the
hydrogen tube. Thus the flame may be made to appear at one or the
other tube at will, only the increase or decrease of the current
of gas must take place by degrees and not suddenly. Further, air
may be taken instead of oxygen, and ordinary coal-gas instead
of hydrogen, and it will then be shown how air burns in an
atmosphere of coal-gas, and it can easily be proved that the lamp
glass is full of a gas combustible in air, because it may be
lighted at the top.
If, instead of hydrogen, any other combustible gas be taken--for
example, ordinary coal gas--then the phenomenon of combustion will
be exactly the same, only a bright flame will be obtained, and the
products of combustion will be different. However, as coal gas contains
a considerable amount of free and combined hydrogen, it will also form a
considerable quantity of water in its combustion.
If hydrogen be mixed with oxygen in the proportion in which they form
water--_i.e._ if two volumes of hydrogen be taken for each volume of
oxygen--then the mixture will be the same as that obtained by the
decomposition of water by a galvanic current--detonating gas.
[Illustration: FIG. 31.--Cavendish's apparatus for exploding detonating
gas. The bell jar standing in the bath is filled with a mixture of two
volumes of hydrogen and one volume of oxygen, and the thick glass vessel
A is then screwed on to it. The air is first pumped out of this vessel,
so that when the stopcock C is opened, it becomes filled with detonating
gas. The stopcock is then re-closed, and the explosion produced by means
of a spark from a Leyden jar. After the explosion has taken place the
stopcock is again opened, and the water rises into the vessel A.]
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