The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
We have already mentioned in the last chapter that the combination of
these gases, or their explosion, may be brought about by the action of
an electric spark, because the spark heats the space through which it
passes, and acts consequently in a manner similar to ignition by means
of contact with an incandescent or burning substance.[29 bis] Cavendish
made this experiment on the ignition of detonating gas, at the end of
the last century, in the apparatus shown in fig. 31. Ignition by the aid
of the electric spark is convenient, for the reason that it may then
be brought about in a closed vessel, and hence chemists still employ
this method when it is required to ignite a mixture of oxygen with a
combustible gas in a closed vessel. For this purpose, especially since
Bunsen's time,[30] an _eudiometer_ is employed. It consists of a thick
glass tube graduated along its length in millimetres (for indicating
the height of the mercury column), and calibrated for a definite volume
(weight of mercury). Two platinum wires are fused into the upper closed
end of the tube, as shown in fig. 32.[31] By the aid of the eudiometer
we may not only determine the volumetric composition of water,[32] and
the quantitative contents of oxygen in air,[33] but also make a number
of experiments explaining the phenomenon of combustion.
[Illustration: FIG. 32.--Eudiometer]
[29 bis] In fact, instead of a spark a fine wire may be taken, and
an electric current passed through it to bring it to a state of
incandescence; in this case there will be no sparks, but the
gases will inflame if the wire be fine enough to become red hot
by the passage of the current.
[30] Now, a great many other different forms of apparatus, sometimes
designed for special purposes, are employed in the laboratory for
the investigation of gases. Detailed descriptions of the methods
of gas analysis, and of the apparatus employed, must be looked
for in works on analytical and applied chemistry.
[31] They must be sealed into the tube in such a manner as to leave
no aperture between them and the glass. In order to test this,
the eudiometer is filled with mercury, and its open end inverted
into mercury. If there be the smallest orifice at the wires, the
external air will enter into the cylinder and the mercury will
fall, although not rapidly if the orifice be very fine.
[32] The eudiometer is used for determining the composition of
combustible gases. A detailed account of _gas analysis_ would be
out of place in this work (_see_ Note 30), but, as an example,
we will give a short description of the determination of the
composition of water by the eudiometer.
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