The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Pure and dry oxygen is first introduced into the eudiometer. When
the eudiometer and the gas in it acquire the temperature of the
surrounding atmosphere--which is recognised by the fact of the
meniscus of the mercury not altering its position during a long
period of time--then the heights at which the mercury stands in
the eudiometer and in the bath are observed. The difference (in
millimetres) gives the height of the column of mercury in the
eudiometer. It must be reduced to the height at which the mercury
would stand at 0° and deducted from the atmospheric pressure, in
order to find the pressure under which the oxygen is measured
(_see_ Chap. I. Note 29). The height of the mercury also shows
the volume of the oxygen. The temperature of the surrounding
atmosphere and the height of the barometric column must also
be observed, in order to know the temperature of the oxygen
and the atmospheric pressure. When the volume of the oxygen
has been measured, pure and dry hydrogen is introduced into
the eudiometer, and the volume of the gases in the eudiometer
again measured. They are then exploded. This is done by a Leyden
jar, whose outer coating is connected by a chain with one wire,
so that a spark passes when the other wire, fused into the
eudiometer, is touched by the terminal of the jar. Or else an
electrophorus is used, or, better still, a Ruhmkorff's coil,
which has the advantage of working equally well in damp or dry
air, whilst a Leyden jar or electrical machine does not act in
damp weather. Further, it is necessary to close the lower orifice
of the eudiometer before the explosion (for this purpose the
eudiometer, which is fixed in a stand, is firmly pressed down
from above on to a piece of india-rubber placed at the bottom
of the bath), as otherwise the mercury and gas would be thrown
out of the apparatus by the explosion. It must also be remarked
that to ensure complete combustion the proportion between the
volumes of oxygen and hydrogen must not exceed twelve of hydrogen
to one volume of oxygen, or fifteen volumes of oxygen to one
volume of hydrogen, because no explosion will take place if one
of the gases be in great excess. It is best to take a mixture
of one volume of hydrogen with several volumes of oxygen. The
combustion will then be complete. It is evident that water is
formed, and that the volume (or tension) is diminished, so that
on opening the end of the eudiometer the mercury will rise in
it. But the tension of the aqueous vapour is now added to the
tension of the gas remaining after the explosion. This must be
taken into account (Chap. I. Note 1). If but little gas remain,
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