The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
the water which is formed will be sufficient for its saturation
with aqueous vapour. This may be learnt from the fact that drops
of water are visible on the sides of the eudiometer after the
mercury has risen in it. If there be none, a certain quantity of
water must be introduced into the eudiometer. Then the number of
millimetres expressing the pressure of the vapour corresponding
with the temperature of the experiment must be subtracted from
the atmospheric pressure at which the remaining gas is measured,
otherwise the result will be inaccurate (Chap. I. Note 1).
This is essentially the method of the determination of the
composition of water which was made for the first time by
Gay-Lussac and Humboldt with sufficient accuracy. Their
determinations led them to the conclusion that water consists of
two volumes of hydrogen (more exactly 2·003, Le Duc 1892), and
one volume of oxygen. Every time they took a greater quantity of
oxygen, the gas remaining after the explosion was oxygen. When
they took an excess of hydrogen, the remaining gas was hydrogen;
and when the oxygen and hydrogen were taken in exactly the above
proportion, neither one nor the other remained. The composition
of water was thus definitely confirmed.
[33] Concerning this application of the eudiometer, see the chapter
on Nitrogen. It may be mentioned as illustrating the various uses
of the eudiometer that Prof. Timeraseeff employed microscopically
small eudiometers to analyse the bubbles of gas given off from
the leaves of plants.
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