The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Thus, for example, it may be demonstrated, by the aid of the eudiometer,
that for the ignition of detonating gas, a _definite temperature_
is required. If the temperature be below that required, combination
will not take place, but if at any spot within the tube it rises to
the temperature of inflammation, then combination will ensue at that
spot, and evolve enough heat for the ignition of the adjacent portions
of the detonating mixture. If to 1 volume of detonating gas there be
added 10 volumes of oxygen, or 4 volumes of hydrogen, or 3 volumes of
carbonic anhydride, then we shall not obtain an explosion by passing a
spark through the diluted mixture. This depends on the fact that the
temperature falls with the dilution of the detonating gas by another
gas, because the heat evolved by the combination of the small quantity
of hydrogen and oxygen brought to incandescence by the spark is not
only transmitted to the water proceeding from the combination, but
also to the foreign substance mixed with the detonating gas.[34] The
necessity of a definite temperature for the ignition of detonating gas
is also seen from the fact that pure detonating gas explodes in the
presence of a red-hot iron wire, or of charcoal heated to 275°, but
with a lower degree of incandescence there is not any explosion. It may
also be brought about by rapid compression, when, as is known, heat
is evolved.[35] Experiments made in the eudiometer showed that the
ignition of detonating gas takes place at a temperature between 450°
and 560°.[36]
[34] Thus 1/4 volume of carbonic oxide, an equal volume of marsh gas,
two volumes of hydrogen chloride or of ammonia, and six volumes
of nitrogen or twelve volumes of air added to one volume of
detonating gas, prevent its explosion.
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