The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Such slow processes of oxidation are always taking place in nature by
the action of the atmosphere. Dead organisms and the substances obtained
from them--such as bodies of animals, wood, wool, grass, &c.--are
especially subject to this action. They _rot_ and _decompose_--that is,
their solid matter is transformed into gases, under the influence of
moisture and atmospheric oxygen, and generally under the influence of
other organisms, such as moulds, worms, micro-organisms (bacteria), and
the like. These are processes of slow combustion, of slow combination
with oxygen. It is well known that manure rots and develops heat,
that stacks of damp hay, damp flour, straw, &c., become heated and
are changed in the process.[47] In all these transformations the same
chief products of combustion are formed as those which are contained
in smoke; the carbon gives carbonic anhydride, and the hydrogen water.
Hence these processes require oxygen just like combustion. This is
the reason why the entire prevention of access of air hinders these
transformations,[48] and an increased supply of air accelerates them.
The mechanical treatment of arable lands by the plough, harrow, and
other similar means has not only the object of facilitating the spread
of roots in the ground, and of making the soil more permeable to water,
but it also serves to facilitate the access of the air to the component
parts of the soil; as a consequence of which the organic remains of soil
rot--so to speak, breathe air and evolve carbonic anhydride. One acre
of good garden land in the course of a summer evolves more than sixteen
tons of carbonic anhydride.
[47] Cotton waste (used in factories for cleaning machines from
lubricating oil) soaked in oil and lying in heaps is
self-combustible, being oxidised by the air.
[48] When it is desired to preserve a supply of vegetable and animal
food, the access of the oxygen of the atmosphere (and also of
the germs of organisms present in the air) is often prevented.
With this object articles of food are often kept in hermetically
closed vessels, from which the air has been withdrawn; vegetables
are dried and soldered up while hot in tin boxes; sardines are
immersed in oil, &c. The removal of water from substances is also
sometimes resorted to with the same object (the drying of hay,
corn, fruits), as also is saturation with substances which absorb
oxygen (such as sulphurous anhydride), or which hinder the growth
of organisms forming the first cause of putrefaction, as in
processes of smoking, embalming, and in the keeping of fishes and
other animal specimens in spirit, &c.
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