The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
It is not only vegetable and animal substances which are subject to slow
oxidation in the presence of water. Some metals even rust under these
conditions. Copper very easily absorbs oxygen in the presence of acids.
Many metallic sulphides (for example, pyrites) are very easily oxidised
with access of air and moisture. Thus processes of slow oxidation
proceed throughout nature. However, there are many elements which do
not under any circumstances combine directly with gaseous oxygen;
nevertheless their compounds with oxygen may be obtained. Platinum,
gold, iridium, chlorine, and iodine are examples of such elements. In
this case recourse is had to a so-called _indirect method_--_i.e._ the
given substance is combined with another element, and by a method of
double decomposition this element is replaced by oxygen. Substances
which do not directly combine with oxygen, but form compounds with it
by an indirect method, often readily lose the oxygen which they had
absorbed by double decomposition or at the moment of its evolution.
Such, for example, are the compounds of oxygen with chlorine, nitrogen,
and platinum, which evolve oxygen on heating--that is, they may be
used as oxidising agents. In this respect _oxidising agents_, or those
compounds of oxygen which are employed in chemical and technical
practice for transferring oxygen to other substances, are especially
remarkable. The most important among these is nitric acid or _aqua
fortis_--a substance rich in oxygen, and capable of evolving it when
heated, which easily oxidises a great number of substances. Thus nearly
all metals and organic substances containing carbon and hydrogen are
more or less oxidised when heated with nitric acid. If strong nitric
acid be taken, and a piece of burning charcoal be immersed in the acid,
it continues to burn. Chromic acid acts like nitric acid; alcohol burns
when mixed with it. Although the action is not so marked, even water
may oxidise with its oxygen. Sodium is not oxidised in perfectly dry
oxygen at the ordinary temperature, but it burns very easily in water
and aqueous vapour. Charcoal can burn in carbonic anhydride--a product
of combustion--forming carbonic oxide. Magnesium burns in the same gas,
separating carbon from it. Speaking generally, combined oxygen can pass
from one compound to another.
The products of combustion or oxidation--and in general the definite
compounds of oxygen--are termed _oxides_. Some oxides are not capable of
combining with other oxides--or combine with only a few, and then with
the evolution of very little heat; others, on the contrary, enter into
combination with very many other oxides, and in general have remarkable
chemical energy. The oxides incapable of combining with others, or only
showing this quality in a small degree, are termed _indifferent oxides_.
Such are the peroxides, of which mention has before been made.
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