The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The class of oxides capable of entering into mutual combination we will
term _saline oxides_. They fall into two chief groups--at least, as
regards the most extreme members. The members of one group combine with
the members of the other group with particular ease. As representative
of one group may be taken the oxides of the metals, magnesium, sodium,
calcium, &c. Representatives of the other group are the oxides formed
by the non-metals, sulphur, phosphorus, carbon. Thus, if we take the
oxide of calcium, or lime, and bring it into contact with oxides of the
second group, combination very readily ensues. For instance, if we mix
calcium oxide with oxide of phosphorus they combine with great facility
and with the evolution of much heat. If we pass the vapour of sulphuric
anhydride, obtained by the combination of sulphurous oxide with oxygen,
over pieces of lime heated to redness, the sulphuric anhydride is
absorbed by the lime with the formation of a substance called calcium
sulphate. The oxides of the first kind, which contain metals, are
termed _basic oxides_ or _bases_. Lime is a familiar example of this
class. The oxides of the second group, which are capable of combining
with the bases, are termed _anhydrides of the acids_ or _acid oxides_.
Sulphuric anhydride, SO_{3}, may be taken as a type of the latter group.
It is a compound of sulphur with oxygen formed not directly but by the
addition of a fresh quantity of oxygen to sulphurous anhydride, SO_{2},
by passing it together with oxygen over incandescent spongy platinum.
Carbonic anhydride (often termed 'carbonic acid'), CO_{2}, phosphoric
anhydride, sulphurous anhydride, are all acid oxides, for they can
combine with such oxides as lime or calcium oxide, magnesia or magnesium
oxide, MgO, soda or sodium oxide, Na_{2}O, &c.
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