The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[16] Gases, like all other substances, may be weighed, but, owing to
their extreme lightness and the difficulty of dealing with them
in large masses, they can only be weighed by very sensitive
balances; that is, in such as, with a considerable load, indicate
a very small difference in weight--for example, a centigram or a
milligram with a load of 1,000 grams. In order to weigh a gas,
a glass globe furnished with a tight-fitting stop-cock is first
of all exhausted of air by an air-pump (a Sprengel pump is the
best). The stop-cock is then closed, and the exhausted globe
weighed. If the gas to be weighed is then let into the globe,
its weight can be determined from the increase in the weight of
the globe. It is necessary, however, that the temperature and
pressure of the air about the balance should remain constant for
both weighings, as the weight of the globe in air will (according
to the laws of hydrostatics) vary with its density. The volume of
the air displaced, and its weight, must therefore be determined
by observing the temperature, density, and moisture of the
atmosphere during the time of experiment. This will be partly
explained later, but may be studied more in detail by physics.
Owing to the complexity of all these operations, the mass of a
gas is usually determined from its volume and density, or from
the weight of a known volume.
[17] The copper carbonate should be dried before weighing, as
otherwise--besides copper oxide and carbonic anhydride--water
will be obtained in the decomposition. Water forms a part of the
composition of malachite, and has therefore to be taken into
consideration. The water produced in the decomposition may be all
collected by absorbing it in sulphuric acid or calcium chloride,
as will be described further on. In order to dry a salt it must
be heated at about 100° until its weight remains constant, or
be placed under an air pump over sulphuric acid, as will also
be presently described. As water is met with almost everywhere,
and as it is absorbed by many substances, the possibility of its
presence should never be lost sight of.
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