The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
3. Red mercury oxide (which is formed as mercury rust by heating
mercury in air) is decomposed like copper carbonate (only by heating
more slowly and at a somewhat higher temperature), with the formation
of the peculiar gas, oxygen. For this purpose the mercury oxide is
placed in a glass tube or retort,[18] to which a gas delivery tube is
attached by means of a cork. This tube is bent downwards, as shown in
the drawing (Fig. 1). The open end of the gas delivery tube is immersed
in a vessel filled with water, called a pneumatic trough.[19] When the
gas begins to be evolved in the retort it is obliged, having no other
outlet, to escape through the gas delivery tube into the water in the
pneumatic trough, and therefore its evolution will be rendered visible
by the bubbles coming from this tube. In heating the retort containing
the mercury oxide, the air contained in the apparatus is first partly
expelled, owing to its expansion by heat, and then the peculiar gas
called 'oxygen' is evolved, and may be easily collected as it comes off.
For this purpose a vessel (an ordinary cylinder, as in the drawing) is
filled quite full with water and its mouth closed; it is then inverted
and placed in this position under the water in the trough; the mouth
is then opened. The cylinder will remain full of water--that is, the
water will remain at a higher level in it than in the surrounding
vessel, owing to the atmospheric pressure. The atmosphere presses on
the surface of the water in the trough, and prevents the water from
flowing out of the cylinder. The mouth of the cylinder is placed over
the end of the gas delivery tube,[20] and the bubbles issuing from it
will rise into the cylinder and displace the water contained in it.
Gases are generally collected in this manner. When a sufficient quantity
of gas has accumulated in the cylinder it can be clearly shown that it
is not air, but another gas which is distinguished by its capacity for
vigorously supporting combustion. In order to show this, the cylinder is
closed, under water, and removed from the bath; its mouth is then turned
upwards, and a smouldering taper plunged into it. As is well known, a
smouldering taper will be extinguished in air, but in the gas which
is given off from red mercury oxide it burns clearly and vigorously,
showing the property possessed by this gas for supporting combustion
more energetically than air, and thus enabling it to be distinguished
from the latter. It may be observed in this experiment that, besides the
formation of oxygen, metallic mercury is formed, which, volatilising at
the high temperature required for the reaction, condenses on the cooler
parts of the retort as a mirror or in globules. Thus two substances,
mercury and oxygen, are obtained by heating red mercury oxide. In this
reaction, from one substance, two new substances are produced--that
is, a decomposition has taken place. The means of collecting and
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