The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
the bright metallic mineral galena, and extracted metallic lead from
it. Thus they saw that from a metallic substance which is unfitted for
use they could obtain another metallic substance which is ductile and
valuable for many technical purposes. Furthermore, they took this lead
and obtained silver, a still more valuable metal, from it. Thus they
might easily conclude that it was possible to ennoble metals by means of
a whole series of transmutations--that is to say, to obtain from them
those which are more and more precious. Having got silver from lead,
they assumed that it would be possible to obtain gold from silver. The
mistake they made was that they never weighed or measured the substances
used or produced in their experiments. Had they done so, they would have
learnt that the weight of the lead was much less than that of the galena
from which it was obtained, and the weight of the silver infinitesimal
compared with that of the lead. Had they looked more closely into
the process of the extraction of the silver from lead (and silver at
the present time is chiefly obtained from the lead ores) they would
have seen that the lead does not change into silver, but that it only
contains a certain small quantity of it, and this amount having once
been separated from the lead it cannot by any further operation give
more. The silver which the alchemists extracted from the lead was in the
lead, and was not obtained by a chemical change of the lead itself. This
is now well known from experiment, but the first view of the nature of
the process was very likely to be an erroneous one.[23] The methods of
research adopted by the alchemists could give but little success, for
they did not set themselves clear and simple questions whose answers
would aid them to make further progress. Thus though they did not
arrive at any exact law, they left nevertheless numerous and useful
experimental data as an inheritance to chemistry; they investigated, in
particular, the transformations proper to metals, and for this reason
chemistry was for long afterwards entirely confined to the study of
metallic substances.
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