The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[24] It is true that Stahl was acquainted with a fact which directly
disproved his hypothesis. It was already known (from the
experiments of Geber, and more especially of Ray, in 1630) that
metals increase in weight by oxidation, whilst, according to
Stahl's hypothesis, they should decrease in weight, because
phlogiston is separated by oxidation. Stahl speaks on this
point as follows:--'I am well aware that metals, in their
transformation into earths, increase in weight. But not only does
this fact not disprove my theory, but, on the contrary, confirms
it, for phlogiston is lighter than air, and, in combining
with substances, strives to lift them, and so decreases their
weight; consequently, a substance which has lost phlogiston
must be heavier.' This argument, it will be seen, is founded
on a misconception of the properties of gases, regarding them
as having no weight and as not being attracted by the earth,
or else on a confused idea of phlogiston itself, since it was
first defined as imponderable. The conception of imponderable
phlogiston tallies well with the habit and methods of the last
century, when recourse was often had to imponderable fluids for
explaining a large number of phenomena. Heat, light, magnetism,
and electricity were explained as being peculiar imponderable
fluids. In this sense the doctrine of Stahl corresponds entirely
with the spirit of his age. If heat be now regarded as motion
or energy, then phlogiston also should be considered in this
light. In fact, in combustion, of coals for instance, heat and
energy are evolved, and not combined in the coal, although the
oxygen and coal do combine. Consequently, the doctrine of Stahl
contains the essence of a true representation of the evolution
of energy, but naturally this evolution is only a consequence of
the combination occurring between the coal and oxygen. As regards
the history of chemistry prior to Lavoisier, besides Stahl's
work (to which reference has been made above), Priestley's
_Experiments and Observations on Different Kinds of Air_, London,
1790, and also Scheele's _Opuscula Chimica et Physica_, Lips.,
1788-89, 2 vols., must be recommended as the two leading works
of the English and Scandinavian chemists showing the condition
of chemical learning before the propagation of Lavoisier's
views, and containing also many important observations which lie
at the basis of the chemistry of our times. A most interesting
memoir on the history of phlogiston is that of Rodwell, in the
_Philosophical Magazine_, 1868, in which it is shown that the
idea of phlogiston dates very far back, that Basil Valentine
(1394-1415), in the _Cursus Triumphalis Antimonii_, Paracelsus
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account