The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In their researches, the alchemists frequently made use of two chemical
processes which are now termed 'reduction' and 'oxidation.' The rusting
of metals, and in general their conversion from a metallic into an
earthy form, is called 'oxidation,' whilst the extraction of a metal
from an earthy substance is called 'reduction.' Many metals--for
instance, iron, lead, and tin--are oxidised by heating in air alone,
and may be again reduced by heating with carbon. Such oxidised metals
are found in the earth, and form the majority of metallic ores. The
metals, such as tin, iron, and copper, may be extracted from these ores
by heating them together with carbon. All these processes were well
studied by the alchemists. It was afterwards shown that all earths and
minerals are formed of similar metallic rusts or oxides, or of their
combinations. Thus the alchemists knew of two forms of chemical changes:
the oxidation of metals and the reduction of the oxides so formed
into metals. The explanation of the nature of these two classes of
chemical phenomena was the means for the discovery of the most important
chemical laws. The first hypothesis on their nature is due to Becker,
and more particularly to Stahl, a surgeon to the King of Prussia.
Stahl writes in his 'Fundamenta Chymiæ,' 1723, that all substances
consist of an imponderable fiery substance called 'phlogiston' (materia
aut principium ignis non ipse ignis), and of another element having
particular properties for each substance. The greater the capacity of
a body for oxidation, or the more combustible it is, the richer it is
in phlogiston. Carbon contains it in great abundance. In oxidation or
combustion phlogiston is emitted, and in reduction it is consumed or
enters into combination. Carbon reduces earthy substances because it is
rich in phlogiston, and gives up a portion of its phlogiston to the
substance reduced. Thus Stahl supposed metals to be compound substances
consisting of phlogiston and an earthy substance or oxide. This
hypothesis is distinguished for its very great simplicity, and for this
and other reasons it acquired many supporters.[24]
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