The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
On pages 24, 25, and 26 a list of the elements, with their symbols and
combining or atomic weights, is given, and we shall see afterwards on
what basis the atomic weights of elements are determined. At present we
will only point out that a compound containing the elements A and B is
designated by the formula A_n_ B_m_, where _m_ and _n_ are the
coefficients or multiples in which the combining weights of the elements
enter into the composition of the substance. If we represent the
combining weight of the substance A by _a_ and that of the substance B by
_b_, then the composition of the substance A_n_ B_m_ will be expressed
thus: it contains _na_ parts by weight of the substance A and _mb_ parts
by weight of the substance B, and consequently 100 parts of our compound
contain _na_ 100/_na_ + _mb_ percentage parts by weight of the substance
A and _mb_ 100/_na_ + _mb_ of the substance B. It is evident that as a
formula shows the relative amounts of all the elements contained in a
compound, the actual weights of the elements contained in a given weight
of a compound may be calculated from its formula. For example, the
formula NaCl of table salt shows (as Na = 23 and Cl = 35·5) that 58·5
lbs. of salt contain 23 lbs. of sodium and 35·5 lbs. of chlorine, and
that 100 parts of it contain 39·3 per cent. of sodium and 60·7 per cent.
of chlorine.
What has been said above clearly limits the province of chemical
changes, because from substances of a given kind there can be obtained
only such as contain the same elements. Even with this limitation,
however, the number of possible combinations is infinitely great. Only
a comparatively small number of compounds have yet been described or
subjected to research, and any one working in this direction may easily
discover new compounds which had not before been obtained. It often
happens, however, that such newly-discovered compounds were foreseen by
chemistry, whose object is the apprehension of that uniformity which
rules over the multitude of compound substances, and whose aim is the
comprehension of those laws which govern their formation and properties.
The conception of elements having been established, the next objects
of chemistry were: the determination of the properties of compound
substances on the basis of the determination of the quantity and kind of
elements of which they are composed; the investigation of the elements
themselves; the determination of what compound substances can be formed
from each element and the properties which these compounds show; and
the apprehension of the nature of the connection between the elements
in different compounds. An element thus serves as the starting point,
and is taken as the primary conception on which all other substances are
built up.
Public-domain text, read in full here on John Shaqi.
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