The Principles of Chemistry, Volume I — John Shaqi
The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
When we state that a certain element enters into the composition of a
given compound (when we say, for instance, that mercury oxide contains
oxygen) we do not mean that it contains oxygen as a gaseous substance,
but only desire to express those transformations which mercury oxide
is capable of making; that is, we wish to say that it is possible to
obtain oxygen from mercury oxide, and that it can give up oxygen to
various other substances; in a word, we desire only to express those
transformations of which mercury oxide is capable. Or, more concisely,
it may be said that the _composition_ of a compound is the expression
of those transformations of which it is capable. It is useful in this
sense to make a clear distinction between the conception of an element
as a _separate_ homogeneous substance, and as a _material_ but invisible
_part_ of a compound. Mercury oxide does not contain two simple bodies,
a gas and a metal, but two elements, mercury and oxygen, which, when
free, are a gas and a metal. Neither mercury as a metal nor oxygen as
a gas is contained in mercury oxide; it only contains the substance of
these elements, just as steam only contains the substance of ice, but
not ice itself, or as corn contains the substance of the seed, but not
the seed itself. The existence of an element may be recognised without
knowing it in the uncombined state, but only from an investigation
of its combinations, and from the knowledge that it gives, under
all possible conditions, substances which are unlike other known
combinations of substances. Fluorine is an example of this kind. It was
for a long time unknown in a free state, and nevertheless was recognised
as an element because its combinations with other elements were known,
and their difference from all other similar compound substances was
determined. In order to grasp the difference between the conception of
the visible form of an element as we know it in the free state, and of
the intrinsic element (or 'radicle,' as Lavoisier called it) contained
in the visible form, it should be remarked that compound substances
also combine together forming yet more complex compounds, and that
they evolve heat in the process of combination. The original compound
may often be extracted from these new compounds by exactly the same
methods as elements are extracted from their corresponding combinations.
Besides, many elements exist under various visible forms whilst the
intrinsic element contained in these various forms is something which is
not subject to change. Thus carbon appears as charcoal, graphite, and
diamond, but yet the element carbon alone, contained in each, is one
and the same. Carbonic anhydride contains carbon, and not charcoal, or
graphite, or the diamond.
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