The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Column 17 gives the specific gravity of the elements in a solid and
a liquid state. An asterisk (*) is placed by those which can either only
be assumed from analogy (for example, the sp. gr. of fluorine and
hydrogen, which have not been obtained in a liquid state), or which vary
very rapidly with a variation of temperature and pressure (like oxygen
and nitrogen), or physical state (for instance, carbon in passing from
the state of charcoal to graphite and diamond). But as the sp. gr. in
general varies with the temperature, mechanical condition, &c., the
figures given, although chosen from the most trustworthy sources, can
only be regarded as approximate, and not as absolutely true. They clearly
show a certain periodicity; for instance, the sp. gr. diminishes from Al
on both sides (Al, Mg, Na, with decreasing atomic weight; and Al, Si, P,
S, Cl, with increasing atomic weight, it also diminishes on both sides
from Cu, Ru, and Os.)
The same remarks refer to the figures in the 18th column, which
gives the so-called atomic volumes of the simple bodies, or the quotient
of their atomic weight and specific gravity. For Na, K, Rb, and Cs the
atomic volume is greatest among the neighbouring elements. For Ni, Pd,
and Os it is least, and this indicates the periodicity of this property
of the simple bodies.
The last (19th) column gives the melting points of the simple
bodies. Here also a periodicity is seen, i.e. a maximum and minimum value
between which there are intermediate values, as we see, for instance, in
the series Cl, K, Ca, Sc, and Ti, or in the series Cr, Mn, Fe, Co, Ni,
Cu, Zn, Ga, and Ge.
* * * * *
CHAPTER XV
THE GROUPING OF THE ELEMENTS AND THE PERIODIC LAW
It is seen from the examples given in the preceding chapters that the sum
of the data concerning the chemical transformations proper to the
elements (for instance, with respect to the formation of acids, salts,
and other compounds having definite properties) is insufficient for
accurately determining the relationship of the elements, inasmuch as this
may be many-sided. Thus, lithium and barium are in some respects
analogous to sodium and potassium, and in others to magnesium and
calcium. It is evident, therefore, that for a complete judgment it is
necessary to have, not only qualitative, but also quantitative, exact and
measurable, data. When a property can be measured it ceases to be vague,
and becomes quantitative instead of merely qualitative.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account