The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Columns 7-14 contain the composition of the saline compounds of the
elements, placed according to their forms, RX, RX_{2} to RX_{8} (in the
14^{th} column). If the element R has a metallic character like H, Li,
Be, &c., then X represents Cl, NO_{3}, 1/2 SO_{4}, &c., haloid radicles,
or (OH) if a perfect hydrate is formed (alkali, aqueous base), or 1/2 O,
1/2 S, &c. when an anhydrous oxide, sulphide, &c. is formed. For
instance, NaCl, Mg(NO_{3})_{2}, Al_{2}(SO_{4})_{3}, correspond to NaX,
MgX_{2}, and AlX_{3}; so also Na(OH), Mg(OH)_{2}, Al(OH)_{3}, Na_{2}O,
MgO, Al_{2}O_{3}, &c. But if the element, like C or N, be of a metalloid
or acid character, X must be regarded as (OH) in the formation of
hydrates; (OM) in the formation of salts, where M is the equivalent of a
metal, 1/2 O in the formation of an anhydride, and Cl in the formation of
a chloranhydride; and in this case (_i.e._ in the acid compounds) Z is
put in the place of X; for example, the formulæ COZ_{2}, NO_{2}Z,
MNO_{2}Z, FeO_{2}Z_{2}, and IZ_{3} correspond to CO(NaO)_{2} =
Na_{2}CO_{3}, COCl_{2}, CO_{2}, NO_{2}(NaO) = NaNO_{3}, NO_{2}Cl,
NO_{2}(OH) = HNO_{3}; MnO_{3}(OK) = KMnO_{4}, ICl, &c.
The 15th column gives the compositions of the peroxides of the
elements, _taking them as anhydrous_. An asterisk (*) is attached to
those of which the composition has not been well established, and a dash
(--) shows that for a given element no peroxides have yet been obtained.
The peroxides contain more oxygen than the higher saline oxides of the
same elements, are powerfully oxidising, and easily give peroxide of
hydrogen. This latter circumstance necessitates their being referred to
the type of peroxide of hydrogen, if bases and acids are referred to the
type of water (see Chapter XV., Note 7 and 11 bis).
The 16th column gives the composition of the lower hydrogen
compounds like N_{3}H and Na_{2}H. They may often be regarded as alloys
of hydrogen, which is frequently disengaged by them at a comparatively
moderate temperature. They differ greatly in their nature from the
hydrogen compounds given in columns 1-4 (_see_ Note 12).
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