The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[8] A glass can only be formed by those slightly volatile oxides which
correspond with feeble acids, like silica, phosphoric and boric
anhydrides, &c., which themselves give glassy masses, like quartz,
glacial phosphoric acid, and boric anhydride. They are able, like
aqueous solutions and like metallic alloys, to solidify either in
an amorphous form or to yield (or even be wholly converted into)
definite crystalline compounds. This view illustrates the position
of solutions amongst the other chemical compounds, and allows all
alloys to be regarded from the aspect of the common laws of
chemical reactions. I have therefore frequently recurred to it in
this work, and have since the year 1850 introduced it into various
provinces of chemistry.
[9] If boric acid in its aqueous solutions proves to be exceedingly
feeble, unenergetic, and easily displaced from its salts by other
acids, yet in an anhydrous state, as anhydride, it exhibits the
properties of an energetic acid oxide, and it _displaces_ the
anhydrides of other acids. This of course does not mean that the
acid then acquires new chemical properties, but only depends on the
fact that the anhydrides of the majority of acids are much more
volatile than boric anhydride, and therefore the salts of many
acids--even of sulphuric acid--are decomposed when fused with boric
anhydride.
By itself boric acid is used in the arts in small quantity, chiefly
for the preservation of meat and fish (which must be afterwards
well washed in water) and of milk, and for soaking the wicks of
stearin candles; the latter application is based on the fact that
the wicks, which are made of cotton twist, contain an ash which is
infusible by itself but which fuses when mixed with boric acid.
Free _boron_ was obtained (1809) by Davy, Gay-Lussac, and Thénard when
they obtained the metals of the alkalis, for boric anhydride when fused
with sodium gives up its oxygen to the sodium, and free boron is
liberated as an _amorphous_ powder like charcoal.[10] It is of a brown
colour, specific gravity 2·45 (Moissan), and when dry does not alter in
the air at the ordinary temperature; but it burns when ignited to 700°,
and in so doing combines not only with the oxygen of the air, but also
with the nitrogen. However, the combustion is never complete, because the
boric anhydride formed on the surface covers the remaining mass of the
boron, and so preserves it from the action of the oxygen. Acids, even
sulphuric (forming SO_{2}) and phosphoric (forming phosphorus), easily
oxidise amorphous boron, especially when heated, converting it into boric
acid. Alkalis have the same action on it, only in this case hydrogen is
evolved. Boron decomposes steam at a red heat, also with evolution of
hydrogen.
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