The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
_Alumina_, Al_{2}O_{3}--that is, the anhydrous aluminium oxide--is
met with in nature, sometimes in a somewhat pure state, having
crystallised in transparent crystals, which are often coloured by
impurities (chromic, cobaltic, and ferric compounds). Such are the ruby
and sapphire, the former red and the latter blue. They have a specific
gravity 4·0, are distinguished by their very great hardness, which is
second only to that of the diamond, and they represent the purest form of
alumina. They are found in Ceylon and other islands of the Indian
Archipelago, embedded in a rock matrix.[18 bis] _Corundum_ is the same
crystallised anhydrous alumina coloured brown by a trace of oxide of
iron. A very much larger portion of this impurity occurs in _emery_,
which is found in crystalline masses in Asia Minor and in Massachusetts,
and owing to its extreme hardness is employed for polishing stones and
metals. In this anhydrous and crystalline state the aluminium oxide is a
substance which very powerfully resists the action of reagents, and is
insoluble both in solutions of the alkalis and in strong acids. It is
only capable of passing into solution after being fused with alkalis.[19]
Alumina may be obtained in this form by artificial means if the hydroxide
be ignited and then fused in the oxyhydrogen flame.[20] Alumina also
occurs in nature in combination with water--as, for instance, in the
rather rare minerals _hydrargillite_ (sp. gr. 2·3), Al_{2}O_{3},3H_{2}O =
2Al(HO)_{3}, and _diaspore_, Al_{2}O_3,H_{2}O = 2AlO(HO) (sp. gr. 3·4). A
less pure hydrate, mixed with ferric oxide, sometimes occurs in masses
(at Baux in the south of France) and is termed _bauxite_; it contains
Al_{2}O_{3},2H_{2}O = Al_{2}O(HO)_{4} (sp. gr. 2·6). When bauxite is
ignited with sodium carbonate, carbonic anhydride is liberated and the
alumina then combines with the sodium oxide, forming a saline aluminate
of the oxides of aluminium and sodium. This is taken advantage of in
practice for the preparation of pure alumina compounds on a large scale,
for bauxite is found in large masses (in the South of France, in Austria,
and in Carolina in South America), and the resultant compound of alumina
and sodium is soluble in water and does not contain ferric oxide. This
solution when subjected to the action of carbonic anhydride gives a
precipitate of aluminium hydroxide,[21] which with acids forms aluminium
salts. If aqueous ammonia be added to a solution of aluminium sulphate a
gelatinous precipitate is formed, which at first remains suspended in the
liquid and then on settling forms a gelatinous mass, which itself
indicates the _colloidal property of aluminium hydroxide_. The following
points are characteristic of this colloidal state: (1) in an anhydrous
state such a colloidal substance is insoluble in water, as alumina is;
(2) in the hydrated state, it is gelatinous and insoluble in water; and
(3) it is also capable of existing in solutions, from which it separates
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