The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
contain one atom of a metal (K, Na, Ca), one atom of a non-metal (C, N),
and three atoms of oxygen. The analogy of form evidently coincides with
an analogy of atomic composition. But, as we have learnt from the
previous description of these salts, there is not any close resemblance
in their properties. It is evident that calcium carbonate approaches more
nearly to magnesium carbonate than to sodium nitrate, although their
crystalline forms are all equally alike. Isomorphous substances which are
perfectly analogous to each other are not only characterised by a close
resemblance of form (homeomorphism), but also by the faculty of entering
into analogous reactions, which is not the case with RNO_{3} and RCO_{3}.
The most important and direct method of recognising perfect
isomorphism--that is, the absolute analogy of two compounds--is given by
that property of analogous compounds of separating from solutions _in
homogeneous crystals, containing the most varied proportions_ of the
analogous substances which enter into their composition. These quantities
do not seem to be in dependence on the molecular or atomic weights, and
if they are governed by any laws they must be analogous to those which
apply to indefinite chemical compounds.[2] This will be clear from the
following examples. Potassium chloride and potassium nitrate are not
isomorphous with each other, and are in an atomic sense composed in a
different manner. If these salts be mixed in a solution and the solution
be evaporated, independent crystals of the two salts will separate, each
in that crystalline form which is proper to it. The crystals will not
contain a mixture of the two salts. But if we mix the solutions of two
isomorphous salts together, then, under certain circumstances, crystals
will be obtained which contain both these substances. However, this
cannot be taken as an absolute rule, for if we take a solution saturated
at a high temperature with a mixture of potassium and sodium chlorides,
then on evaporation sodium chloride only will separate, and on cooling
only potassium chloride. The first will contain very little potassium
chloride, and the latter very little sodium chloride.[3] But if we take,
for example, a mixture of solutions of magnesium sulphate and zinc
sulphate, they cannot be separated from each other by evaporating the
mixture, notwithstanding the rather considerable difference in the
solubility of these salts. Again, the isomorphous salts, magnesium
carbonate, and calcium carbonate are found together--that is, in one
crystal--in nature. The angle of the rhombohedron of these magnesia-lime
spars is intermediate between the angles proper to the two spars
individually (for calcium carbonate, the angle of the rhombohedron is
105° 8´; magnesium carbonate, 107° 30´; CaMg(CO_{3})_{2}, 106° 10´).
Certain of these _isomorphous mixtures_ of calc and magnesia spars appear
in well-formed crystals, and in this case there not unfrequently exists a
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