The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
simple molecular proportion of strictly definite chemical combination
between the component salts--for instance, CaCO_{3},MgCO_{3}--whilst in
other cases, especially in the absence of distinct crystallisation (in
dolomites), no such simple molecular proportion is observable: this is
also the case in many artificially prepared isomorphous mixtures. The
microscopical and crystallo-optical researches of Professor Inostrantzoff
and others show that in many cases there is really a mechanical, although
microscopically minute, juxtaposition in one whole of the heterogeneous
crystals of calcium carbonate (double refracting) and of the compound
CaMgC_{2}O_{6}. If we suppose the adjacent parts to be microscopically
small (on the basis of the researches of Mallard, Weruboff, and others),
we obtain an idea of isomorphous mixtures. A formula of the following
kind is given to isomorphous mixtures: for instance, for spars, RCO_{3},
where R = Mg, Ca, and where it may be Fe,Mn ..., &c. This means that the
Ca is partially replaced by Mg or another metal. Alums form a common
example of the separation of isomorphous mixtures from solutions. They
are double sulphates (or seleniates) of alumina (or oxides isomorphous
with it) and the alkalis, which crystallise in well-formed crystals. If
aluminium sulphate be mixed with potassium sulphate, an alum separates,
having the composition KAlS_{2}O_{8},12H_{2}O. If sodium sulphate or
ammonium sulphate, or rubidium (or thallium) sulphate be used, we obtain
alums having the composition RAlS_{2}O_{8},12H_{2}O. Not only do they all
crystallise in the cubic system, but they also contain an equal atomic
quantity of water of crystallisation (12H_{2}O). Besides which, if we mix
solutions of the potassium and ammonium (NH_{4}AlS_{2}O_{8},12H_{2}O)
alums together, then the crystals which separate will contain various
proportions of the alkalis taken, and separate crystals of the alums of
one or the other kind will not be obtained, but each separate crystal
will contain both potassium and ammonium. Nor is this all; if we take a
crystal of a potassium alum and immerse it in a solution capable of
yielding ammonia alum, the crystal of the potash alum will continue to
grow and increase in size in this solution--that is, a layer of the
ammonia or other alum will deposit itself upon the planes bounding the
crystal of the potash alum. This is very distinctly seen if a colourless
crystal of a common alum be immersed in a saturated violet solution of
chrome alum, KCrS_{2}O_{8},12H_{2}O, which then deposits itself in a
violet layer over the colourless crystal of the alumina alum, as was
observed even before Mitscherlich noticed it. If this crystal be then
immersed in a solution of an alumina alum, a layer of this salt will form
over the layer of chrome alum, so that one alum is able to incite the
growth of the other. If the deposition proceed simultaneously, the
resultant intermixture may be minute and inseparable, but its nature is
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account