The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[2] Solutions furnish the commonest examples of indefinite chemical
compounds. But the isomorphous mixtures which are so common among
the crystalline compounds of silica forming the crust of the earth,
as well as alloys, which are so important in the application of
metals to the arts, are also instances of indefinite compounds. And
if in Chapter I., and in many other portions of this work, it has
been necessary to admit the presence of definite compounds (in a
state of dissociation) in solutions, the same applies with even
greater force to isomorphous mixtures and alloys. For this reason
in many places in this work I refer to facts which compel us to
recognise the existence of definite chemical compounds in all
isomorphous mixtures and alloys. This view of mine (which dates
from the sixties) upon isomorphous mixtures finds a particularly
clear confirmation in B. Roozeboom's researches (1892) upon the
solubility and crystallising capacity of mixtures of the chlorates
of potassium and thallium, KClO_{3} and TlClO_{3}. He showed that
when a solution contains different amounts of these salts, it
deposits crystals containing either an excess of the first salt,
from 98 p.c. to 100 p.c., or an excess of the second salt, from
63·7 to 100 p.c.; that is, in the crystalline form, either the
first salt saturates the second or the second the first, just as in
the solution of ether in water (Chapter I.); moreover, the
solubility of the mixtures containing 36·3 and 98 p.c. KClO_{3} is
similar, just as the vapour tension of a saturated solution of
water in ether is equal to that of a saturated solution of ether in
water (Chapter I., Note 47). But just as there are solutions
miscible in all proportions, so also certain isomorphous bodies can
be present in crystals in all possible proportions of their
component parts. Van 't Hoff calls such systems 'solid solutions.'
These views were subsequently elaborated by Nernst (1892), and Witt
(1891) applied them in explaining the phenomena observed in the
coloration of tissues.
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