The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
understood from the preceding experiments; the attractive force of
crystallisation of isomorphous substances is so nearly equal that the
attractive power of an isomorphous substance induces a crystalline
superstructure exactly the same as would be produced by the attractive
force of like crystalline particles. From this it is evident that one
isomorphous substance may _induce the crystallisation_[4] of another.
Such a phenomenon explains, on the one hand, the aggregation of different
isomorphous substances in one crystal, whilst, on the other hand, it
serves as a most exact indication of the nearness both of the molecular
composition of isomorphous substances and of those forces which are
proper to the elements which distinguish the isomorphous substances.
Thus, for example, ferrous sulphate or green vitriol crystallises in the
monoclinic system and contains seven molecules of water,
FeSO_{4},7H_{2}O, whilst copper vitriol crystallises with five molecules
of water in the triclinic system, CuSO_{4},5H_{2}O; nevertheless, it may
be easily proved that both salts are perfectly isomorphous; that they are
able to appear in identically the same forms and with an equal molecular
amount of water. For instance, Marignac, by evaporating a mixture of
sulphuric acid and ferrous sulphate under the receiver of an air-pump,
first obtained crystals of the hepta-hydrated salt, and then of the
penta-hydrated salt FeSO_{4},5H_{2}O, which were perfectly similar to the
crystals of copper sulphate. Furthermore, Lecoq de Boisbaudran, by
immersing crystals of FeSO_{4},7H_{2}O in a supersaturated solution of
copper sulphate, caused the latter to deposit in the same form as ferrous
sulphate, in crystals of the monoclinic system, CuSO_{4},7H_{2}O.
[1] For instance the analogy of the sulphates of K, Rb, and Cs (Chapter
XIII., Note 1).
[1 bis] The crystalline forms of aragonite, strontianite, and witherite
belong to the rhombic system; the angle of the prism of CaCO_{3} is
116° 10´, of SrCO_{3} 117° 19´, and of BaCO_{3} 118° 30´. On the
other hand the crystalline forms of calc spar, magnesite, and
calamine, which resemble each other quite as closely, belong to the
rhombohedral system, with the angle of the rhombohedra for CaCO_{3}
105° 8´, MgCO_{3} 107° 10´, and ZnCO_{3} 107° 40´. From this
comparison it is at once evident that zinc is more closely allied
to magnesium than magnesium to calcium.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account