The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Silica, as regards its _salt forming properties_, stands in the series of
oxides on the boundary line on the side of the acids in just such a place
as alumina occupies on the side of the bases--that is, aluminium
hydroxide is the representative of the feeblest bases and silicic acid is
the least energetic of acids (at least in the presence of water--that is,
in aqueous solutions); in alumina, however, the basic properties are
distinctly expressed, while in silica the acid properties preponderate.
Like all feeble acid oxides it is capable of forming, with other acids,
saline compounds which are but slightly stable and are very easily
decomposed in the presence of water. The chief peculiarity of the
silicates consists in the number of their types. The salts formed with
nitric or sulphuric acid exist in one, two, and three tolerably stable
forms, but for acids like silicic acid the number of forms is very great,
almost unlimited. The natural silicates in particular furnish proof of
this fact; they contain various bases in combination with silica, and for
one and the same base there often exist various degrees of combination.
As feeble bases are capable of forming basic salts in addition to normal
salts--that is, a compound of a normal salt with a feeble base (either
the hydroxide or the oxide)--so the feeble acid oxides (although not all)
form, in addition to normal salts, highly acid salts--that is, normal
salts _plus_ acid (hydrate or anhydride). Such acids are boric,
phosphoric, molybdic, chromic, and especially silicic, acid.
In order to explain these relations it is necessary first to recollect
the existence of the various hydrates of silica, or silicic acids,[20]
and then to turn our attention to the similarity between silicon
compounds and metallic alloys. Silica is an oxide having the appearance
of, and in many respects the same properties as, those oxides which
combine with it, and if two metals are capable of forming homogeneous
alloys in which there exist definite or indefinite compounds, it is
permissible to assume a similar power of forming alloys in the case of
analogous oxides. Such alloys are found in indefinite, amorphous masses
in the form of glass, lava, slags, and a number of similar siliceous
compounds which do not contain any definite types of combination, but
nevertheless are homogeneous throughout their mass. By slow cooling, or
under other circumstances, definite crystalline compounds may--and
sometimes do--separate from this homogeneous mass, as also sometimes
definite crystalline alloys separate from metallic alloys.
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